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(4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide molecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intramolecular C—H⋯O hydrogen bonds and...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011543/ https://www.ncbi.nlm.nih.gov/pubmed/21589277 http://dx.doi.org/10.1107/S1600536810046763 |
Sumario: | In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide molecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intramolecular C—H⋯O hydrogen bonds and intermolecular π–π stacking interactions between the pyridine rings [centroid–centroid distances = 3.637 (4) and 3.818 (4) Å] are present in the crystal structure. |
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