(4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)

In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonds and...

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Detalles Bibliográficos
Autor principal: Yousefi, Mohammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011543/
https://www.ncbi.nlm.nih.gov/pubmed/21589277
http://dx.doi.org/10.1107/S1600536810046763
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author Yousefi, Mohammad
author_facet Yousefi, Mohammad
author_sort Yousefi, Mohammad
collection PubMed
description In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonds and inter­molecular π–π stacking inter­actions between the pyridine rings [centroid–centroid distances = 3.637 (4) and 3.818 (4) Å] are present in the crystal structure.
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spelling pubmed-30115432010-12-30 (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II) Yousefi, Mohammad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnI(2)(C(12)H(12)N(2))(C(2)H(6)OS)], the Zn(II) ion is coordinated by two N atoms from a 4,4′-dimethyl-2,2′-bipyridine ligand, one O atom from a dimethyl sulfoxide mol­ecule and two I atoms in a distorted trigonal-bipyramidal geometry. Intra­molecular C—H⋯O hydrogen bonds and inter­molecular π–π stacking inter­actions between the pyridine rings [centroid–centroid distances = 3.637 (4) and 3.818 (4) Å] are present in the crystal structure. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011543/ /pubmed/21589277 http://dx.doi.org/10.1107/S1600536810046763 Text en © Mohammad Yousefi 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yousefi, Mohammad
(4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
title (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
title_full (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
title_fullStr (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
title_full_unstemmed (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
title_short (4,4′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)(dimethyl sulfoxide-κO)diiodidozinc(II)
title_sort (4,4′-dimethyl-2,2′-bipyridine-κ(2) n,n′)(dimethyl sulfoxide-κo)diiodidozinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011543/
https://www.ncbi.nlm.nih.gov/pubmed/21589277
http://dx.doi.org/10.1107/S1600536810046763
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