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catena-Poly[[[aquatris(pyridine-κN)nickel(II)]-μ-2,3,5,6-tetrachlorobenzene-1,4-dicarboxylato-κ(2) O (1):O (4)] pyridine monosolvate]
The asymmetric unit of the title compound, {[Ni(C(8)Cl(4)O(4))(C(5)H(5)N)(3)(H(2)O)]·C(5)H(5)N}(n), contains two independent nickel(II) cations displaying a distorted octahedral coordination geometry provided by the N atoms of three pyridine molecules, the O atom of a water molecule, and O atoms...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011545/ https://www.ncbi.nlm.nih.gov/pubmed/21589294 http://dx.doi.org/10.1107/S1600536810045794 |
Sumario: | The asymmetric unit of the title compound, {[Ni(C(8)Cl(4)O(4))(C(5)H(5)N)(3)(H(2)O)]·C(5)H(5)N}(n), contains two independent nickel(II) cations displaying a distorted octahedral coordination geometry provided by the N atoms of three pyridine molecules, the O atom of a water molecule, and O atoms of two monodentate μ(2)-bridging tetrachloroterephthalate dianions. The metal atoms are linked by the dianions into zigzag chains running parallel to [11[Image: see text]]. The crystal packing is stabilized by O—H⋯N and O—H⋯O hydrogen bonds. |
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