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Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)

In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra­dentate triethano­lamine ligand, and one N atom from an azide ligand. The O atoms define...

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Detalles Bibliográficos
Autores principales: Liu, Yan-Ju, Yang, Huai-Xia, Yuan, Juan, Wang, Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011546/
https://www.ncbi.nlm.nih.gov/pubmed/21589293
http://dx.doi.org/10.1107/S1600536810047100
Descripción
Sumario:In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra­dentate triethano­lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O—H⋯O hydrogen-bonding inter­actions between the ethanol OH groups and the ethano­late O atom of a neighbouring complex into chains running parallel to [010].