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Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4) N,O,O′,O′′}cobalt(II)
In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetradentate triethanolamine ligand, and one N atom from an azide ligand. The O atoms define...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011546/ https://www.ncbi.nlm.nih.gov/pubmed/21589293 http://dx.doi.org/10.1107/S1600536810047100 |
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author | Liu, Yan-Ju Yang, Huai-Xia Yuan, Juan Wang, Xia |
author_facet | Liu, Yan-Ju Yang, Huai-Xia Yuan, Juan Wang, Xia |
author_sort | Liu, Yan-Ju |
collection | PubMed |
description | In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetradentate triethanolamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O—H⋯O hydrogen-bonding interactions between the ethanol OH groups and the ethanolate O atom of a neighbouring complex into chains running parallel to [010]. |
format | Text |
id | pubmed-3011546 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30115462010-12-30 Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4) N,O,O′,O′′}cobalt(II) Liu, Yan-Ju Yang, Huai-Xia Yuan, Juan Wang, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetradentate triethanolamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O—H⋯O hydrogen-bonding interactions between the ethanol OH groups and the ethanolate O atom of a neighbouring complex into chains running parallel to [010]. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011546/ /pubmed/21589293 http://dx.doi.org/10.1107/S1600536810047100 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Liu, Yan-Ju Yang, Huai-Xia Yuan, Juan Wang, Xia Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4) N,O,O′,O′′}cobalt(II) |
title | Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4)
N,O,O′,O′′}cobalt(II) |
title_full | Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4)
N,O,O′,O′′}cobalt(II) |
title_fullStr | Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4)
N,O,O′,O′′}cobalt(II) |
title_full_unstemmed | Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4)
N,O,O′,O′′}cobalt(II) |
title_short | Azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4)
N,O,O′,O′′}cobalt(II) |
title_sort | azido{2-[bis(2-hydroxyethyl)amino]ethanolato-κ(4)
n,o,o′,o′′}cobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011546/ https://www.ncbi.nlm.nih.gov/pubmed/21589293 http://dx.doi.org/10.1107/S1600536810047100 |
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