Cargando…

Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)

In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra­dentate triethano­lamine ligand, and one N atom from an azide ligand. The O atoms define...

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Yan-Ju, Yang, Huai-Xia, Yuan, Juan, Wang, Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011546/
https://www.ncbi.nlm.nih.gov/pubmed/21589293
http://dx.doi.org/10.1107/S1600536810047100
_version_ 1782194967758766080
author Liu, Yan-Ju
Yang, Huai-Xia
Yuan, Juan
Wang, Xia
author_facet Liu, Yan-Ju
Yang, Huai-Xia
Yuan, Juan
Wang, Xia
author_sort Liu, Yan-Ju
collection PubMed
description In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra­dentate triethano­lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O—H⋯O hydrogen-bonding inter­actions between the ethanol OH groups and the ethano­late O atom of a neighbouring complex into chains running parallel to [010].
format Text
id pubmed-3011546
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30115462010-12-30 Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II) Liu, Yan-Ju Yang, Huai-Xia Yuan, Juan Wang, Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(6)H(14)NO(3))(N(3))] or [Co(teaH(2))N(3)], the Co(II) atom resides in a trigonal–bipymidal O(3)N(2) environment formed by three O atoms and one N atom from a simply deprotonated tetra­dentate triethano­lamine ligand, and one N atom from an azide ligand. The O atoms define the equatorial plane whereas both N atoms are in axial positions. The mononuclear units are linked through O—H⋯O hydrogen-bonding inter­actions between the ethanol OH groups and the ethano­late O atom of a neighbouring complex into chains running parallel to [010]. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011546/ /pubmed/21589293 http://dx.doi.org/10.1107/S1600536810047100 Text en © Liu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Yan-Ju
Yang, Huai-Xia
Yuan, Juan
Wang, Xia
Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)
title Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)
title_full Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)
title_fullStr Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)
title_full_unstemmed Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)
title_short Azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) N,O,O′,O′′}cobalt(II)
title_sort azido­{2-[bis­(2-hy­droxy­eth­yl)amino]­ethano­lato-κ(4) n,o,o′,o′′}cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011546/
https://www.ncbi.nlm.nih.gov/pubmed/21589293
http://dx.doi.org/10.1107/S1600536810047100
work_keys_str_mv AT liuyanju azido2bis2hydroxyethylaminoethanolatok4nooocobaltii
AT yanghuaixia azido2bis2hydroxyethylaminoethanolatok4nooocobaltii
AT yuanjuan azido2bis2hydroxyethylaminoethanolatok4nooocobaltii
AT wangxia azido2bis2hydroxyethylaminoethanolatok4nooocobaltii