[1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)

In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra­hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37 (2)°. The two N ato...

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Detalles Bibliográficos
Autores principales: Li, Haoyang, Xiang, Yonggang, Han, Hongfei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011549/
https://www.ncbi.nlm.nih.gov/pubmed/21589280
http://dx.doi.org/10.1107/S1600536810046787
Descripción
Sumario:In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra­hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37 (2)°. The two N atoms of the guanidinato ligand exhibit an almost uniform affinity to the metal atom.

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