[1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)

In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra­hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37 (2)°. The two N ato...

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Detalles Bibliográficos
Autores principales: Li, Haoyang, Xiang, Yonggang, Han, Hongfei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011549/
https://www.ncbi.nlm.nih.gov/pubmed/21589280
http://dx.doi.org/10.1107/S1600536810046787
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author Li, Haoyang
Xiang, Yonggang
Han, Hongfei
author_facet Li, Haoyang
Xiang, Yonggang
Han, Hongfei
author_sort Li, Haoyang
collection PubMed
description In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra­hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37 (2)°. The two N atoms of the guanidinato ligand exhibit an almost uniform affinity to the metal atom.
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spelling pubmed-30115492010-12-30 [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III) Li, Haoyang Xiang, Yonggang Han, Hongfei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra­hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37 (2)°. The two N atoms of the guanidinato ligand exhibit an almost uniform affinity to the metal atom. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011549/ /pubmed/21589280 http://dx.doi.org/10.1107/S1600536810046787 Text en © Li et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Haoyang
Xiang, Yonggang
Han, Hongfei
[1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)
title [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)
title_full [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)
title_fullStr [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)
title_full_unstemmed [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)
title_short [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III)
title_sort [1,1-(butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011549/
https://www.ncbi.nlm.nih.gov/pubmed/21589280
http://dx.doi.org/10.1107/S1600536810046787
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AT xiangyonggang 11butane14diyl23dicyclohexylguanidinatodimethylaluminumiii
AT hanhongfei 11butane14diyl23dicyclohexylguanidinatodimethylaluminumiii

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