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Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octahedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hydroxyethylpyridine (HEP) bridging lig...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011554/ https://www.ncbi.nlm.nih.gov/pubmed/21589279 http://dx.doi.org/10.1107/S1600536810046891 |
Sumario: | In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octahedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hydroxyethylpyridine (HEP) bridging ligands, two N atoms from two HEP ligands and one azido ligand, while the other Co(II) atom is coordinated by the same three O atoms, one N atom from an HEP ligand and two azido ligands. Weak intermolecular C—H⋯N hydrogen bonds link the dinuclear complexes into corrugated layers parallel to the bc plane. These layers are further packed with the formation of channels propagating in [010] and filled with the disordered [in a ratio 0.691 (13):0.309 (13)] acetonitrile solvate molecules. |
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