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Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octahedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hydroxyethylpyridine (HEP) bridging lig...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011554/ https://www.ncbi.nlm.nih.gov/pubmed/21589279 http://dx.doi.org/10.1107/S1600536810046891 |
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author | Yang, Jie Liu, Shizheng Lv, Lei Li, Dacheng |
author_facet | Yang, Jie Liu, Shizheng Lv, Lei Li, Dacheng |
author_sort | Yang, Jie |
collection | PubMed |
description | In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octahedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hydroxyethylpyridine (HEP) bridging ligands, two N atoms from two HEP ligands and one azido ligand, while the other Co(II) atom is coordinated by the same three O atoms, one N atom from an HEP ligand and two azido ligands. Weak intermolecular C—H⋯N hydrogen bonds link the dinuclear complexes into corrugated layers parallel to the bc plane. These layers are further packed with the formation of channels propagating in [010] and filled with the disordered [in a ratio 0.691 (13):0.309 (13)] acetonitrile solvate molecules. |
format | Text |
id | pubmed-3011554 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30115542010-12-30 Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate Yang, Jie Liu, Shizheng Lv, Lei Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octahedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hydroxyethylpyridine (HEP) bridging ligands, two N atoms from two HEP ligands and one azido ligand, while the other Co(II) atom is coordinated by the same three O atoms, one N atom from an HEP ligand and two azido ligands. Weak intermolecular C—H⋯N hydrogen bonds link the dinuclear complexes into corrugated layers parallel to the bc plane. These layers are further packed with the formation of channels propagating in [010] and filled with the disordered [in a ratio 0.691 (13):0.309 (13)] acetonitrile solvate molecules. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011554/ /pubmed/21589279 http://dx.doi.org/10.1107/S1600536810046891 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yang, Jie Liu, Shizheng Lv, Lei Li, Dacheng Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate |
title | Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate |
title_full | Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate |
title_fullStr | Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate |
title_full_unstemmed | Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate |
title_short | Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate |
title_sort | triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(ii) acetonitrile monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011554/ https://www.ncbi.nlm.nih.gov/pubmed/21589279 http://dx.doi.org/10.1107/S1600536810046891 |
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