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Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate

In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octa­hedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hy­droxy­ethyl­pyridine (HEP) bridging lig...

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Detalles Bibliográficos
Autores principales: Yang, Jie, Liu, Shizheng, Lv, Lei, Li, Dacheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011554/
https://www.ncbi.nlm.nih.gov/pubmed/21589279
http://dx.doi.org/10.1107/S1600536810046891
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author Yang, Jie
Liu, Shizheng
Lv, Lei
Li, Dacheng
author_facet Yang, Jie
Liu, Shizheng
Lv, Lei
Li, Dacheng
author_sort Yang, Jie
collection PubMed
description In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octa­hedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hy­droxy­ethyl­pyridine (HEP) bridging ligands, two N atoms from two HEP ligands and one azido ligand, while the other Co(II) atom is coordinated by the same three O atoms, one N atom from an HEP ligand and two azido ligands. Weak inter­molecular C—H⋯N hydrogen bonds link the dinuclear complexes into corrugated layers parallel to the bc plane. These layers are further packed with the formation of channels propagating in [010] and filled with the disordered [in a ratio 0.691 (13):0.309 (13)] acetonitrile solvate mol­ecules.
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spelling pubmed-30115542010-12-30 Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate Yang, Jie Liu, Shizheng Lv, Lei Li, Dacheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(2)(C(7)H(8)NO)(3)(N(3))(3)]·CH(3)CN, the two Co(II) ions in the dinuclear complex have different coordination environments, both in a distorted octa­hedral geometry. One Co(II) atom is coordinated by three O atoms from the three 2-hy­droxy­ethyl­pyridine (HEP) bridging ligands, two N atoms from two HEP ligands and one azido ligand, while the other Co(II) atom is coordinated by the same three O atoms, one N atom from an HEP ligand and two azido ligands. Weak inter­molecular C—H⋯N hydrogen bonds link the dinuclear complexes into corrugated layers parallel to the bc plane. These layers are further packed with the formation of channels propagating in [010] and filled with the disordered [in a ratio 0.691 (13):0.309 (13)] acetonitrile solvate mol­ecules. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011554/ /pubmed/21589279 http://dx.doi.org/10.1107/S1600536810046891 Text en © Yang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Jie
Liu, Shizheng
Lv, Lei
Li, Dacheng
Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
title Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
title_full Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
title_fullStr Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
title_full_unstemmed Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
title_short Triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(II) acetonitrile monosolvate
title_sort triazidotris[μ-2-(2-pyridyl)ethanolato]dicobalt(ii) acetonitrile monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011554/
https://www.ncbi.nlm.nih.gov/pubmed/21589279
http://dx.doi.org/10.1107/S1600536810046891
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