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Bis[μ-2,2′-dimethyl-1,1′-(3-oxapentane-1,5-diyl)di-1H-benzimidazole-κ(2) N (3):N (3′)]bis[bis(4-methoxybenzoato)-κO;κ(2) O,O′-cobalt(II)]
The complete molecule of the title complex, [Co(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], is a dimer of the paddle-wheel-type generated by crystallographic inversion symmetry. The Co(II) ion is pentacoordinated by three O atoms from two 4-methoxybenzoate anions (one bidentate and one monodentate...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011569/ https://www.ncbi.nlm.nih.gov/pubmed/21589242 http://dx.doi.org/10.1107/S160053681004568X |
Sumario: | The complete molecule of the title complex, [Co(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], is a dimer of the paddle-wheel-type generated by crystallographic inversion symmetry. The Co(II) ion is pentacoordinated by three O atoms from two 4-methoxybenzoate anions (one bidentate and one monodentate) and two N atoms from two 2,2′-bis(2-methyl-1H-benzimidazole)ether ligands. This results in a very distorted trigonal–bipyramidal geometry for the metal ion, with both N atoms in equatorial sites. The dihedral angle between the benzimidazole ring systems in the ligand is 60.04 (8)°. The configuration of the molecule is supported by intramolecular C—H⋯O hydrogen bonds. |
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