(4-tert-Butyl­pyridine)­chlorido[hydro­tris­(3,5-dimethyl­pyrazol-1-yl)borato]nitro­sylmolybdenum(I) dichloro­methane monosolvate

In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octa­hedral geometry with the hydro­tris­(3,5-dimethyl­pyrazol­yl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butyl­pyrine ligand, chloride a...

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Detalles Bibliográficos
Autores principales: Kassim, Mohammad B., McCleverty, Jon A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011577/
https://www.ncbi.nlm.nih.gov/pubmed/21589350
http://dx.doi.org/10.1107/S1600536810048233
Descripción
Sumario:In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octa­hedral geometry with the hydro­tris­(3,5-dimethyl­pyrazol­yl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butyl­pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intra­molecular C—H⋯Cl hydrogen bond helps to stabilize the configuration of the complex mol­ecule. The packing is stabilized by an inter­molecular C—H⋯Cl hydrogen bond involving the complex mol­ecule and the CH(2)Cl(2) solvent mol­ecule.

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