Cargando…
(4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate
In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octahedral geometry with the hydrotris(3,5-dimethylpyrazolyl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butylpyrine ligand, chloride a...
| Autores principales: | , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011577/ https://www.ncbi.nlm.nih.gov/pubmed/21589350 http://dx.doi.org/10.1107/S1600536810048233 |
| _version_ | 1782194975385059328 |
|---|---|
| author | Kassim, Mohammad B. McCleverty, Jon A. |
| author_facet | Kassim, Mohammad B. McCleverty, Jon A. |
| author_sort | Kassim, Mohammad B. |
| collection | PubMed |
| description | In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octahedral geometry with the hydrotris(3,5-dimethylpyrazolyl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butylpyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intramolecular C—H⋯Cl hydrogen bond helps to stabilize the configuration of the complex molecule. The packing is stabilized by an intermolecular C—H⋯Cl hydrogen bond involving the complex molecule and the CH(2)Cl(2) solvent molecule. |
| format | Text |
| id | pubmed-3011577 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30115772010-12-30 (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate Kassim, Mohammad B. McCleverty, Jon A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octahedral geometry with the hydrotris(3,5-dimethylpyrazolyl)borate anion in an N,N′,N′′-tridentate tripodal (facial) coordination mode. A 4-tert-butylpyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intramolecular C—H⋯Cl hydrogen bond helps to stabilize the configuration of the complex molecule. The packing is stabilized by an intermolecular C—H⋯Cl hydrogen bond involving the complex molecule and the CH(2)Cl(2) solvent molecule. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011577/ /pubmed/21589350 http://dx.doi.org/10.1107/S1600536810048233 Text en © Kassim and McCleverty 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kassim, Mohammad B. McCleverty, Jon A. (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate |
| title | (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate |
| title_full | (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate |
| title_fullStr | (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate |
| title_full_unstemmed | (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate |
| title_short | (4-tert-Butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(I) dichloromethane monosolvate |
| title_sort | (4-tert-butylpyridine)chlorido[hydrotris(3,5-dimethylpyrazol-1-yl)borato]nitrosylmolybdenum(i) dichloromethane monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011577/ https://www.ncbi.nlm.nih.gov/pubmed/21589350 http://dx.doi.org/10.1107/S1600536810048233 |
| work_keys_str_mv | AT kassimmohammadb 4tertbutylpyridinechloridohydrotris35dimethylpyrazol1ylboratonitrosylmolybdenumidichloromethanemonosolvate AT mcclevertyjona 4tertbutylpyridinechloridohydrotris35dimethylpyrazol1ylboratonitrosylmolybdenumidichloromethanemonosolvate |