Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)

In the dinuclear centrosymmetric title complex, [Li(2)(C(17)H(30)N(3))(2)(C(4)H(8)O)(2)], the Li(+) cation is coordinated by three N atoms from two guanidinate ligands and an O atom from tetra­hydro­furan (THF) in a strongly distorted tetrahedral environment. In the guanidinate-bridged THF-stabilize...

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Detalles Bibliográficos
Autores principales: Han, Hongfei, Li, Wenjuan, Li, Haoyang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011579/
https://www.ncbi.nlm.nih.gov/pubmed/21589264
http://dx.doi.org/10.1107/S1600536810046477
Descripción
Sumario:In the dinuclear centrosymmetric title complex, [Li(2)(C(17)H(30)N(3))(2)(C(4)H(8)O)(2)], the Li(+) cation is coordinated by three N atoms from two guanidinate ligands and an O atom from tetra­hydro­furan (THF) in a strongly distorted tetrahedral environment. In the guanidinate-bridged THF-stabilized dimer the Li⋯Li separation is short at 2.479 (8) Å.

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