Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)

In the dinuclear centrosymmetric title complex, [Li(2)(C(17)H(30)N(3))(2)(C(4)H(8)O)(2)], the Li(+) cation is coordinated by three N atoms from two guanidinate ligands and an O atom from tetra­hydro­furan (THF) in a strongly distorted tetrahedral environment. In the guanidinate-bridged THF-stabilize...

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Detalles Bibliográficos
Autores principales: Han, Hongfei, Li, Wenjuan, Li, Haoyang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011579/
https://www.ncbi.nlm.nih.gov/pubmed/21589264
http://dx.doi.org/10.1107/S1600536810046477
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author Han, Hongfei
Li, Wenjuan
Li, Haoyang
author_facet Han, Hongfei
Li, Wenjuan
Li, Haoyang
author_sort Han, Hongfei
collection PubMed
description In the dinuclear centrosymmetric title complex, [Li(2)(C(17)H(30)N(3))(2)(C(4)H(8)O)(2)], the Li(+) cation is coordinated by three N atoms from two guanidinate ligands and an O atom from tetra­hydro­furan (THF) in a strongly distorted tetrahedral environment. In the guanidinate-bridged THF-stabilized dimer the Li⋯Li separation is short at 2.479 (8) Å.
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spelling pubmed-30115792010-12-30 Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li) Han, Hongfei Li, Wenjuan Li, Haoyang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the dinuclear centrosymmetric title complex, [Li(2)(C(17)H(30)N(3))(2)(C(4)H(8)O)(2)], the Li(+) cation is coordinated by three N atoms from two guanidinate ligands and an O atom from tetra­hydro­furan (THF) in a strongly distorted tetrahedral environment. In the guanidinate-bridged THF-stabilized dimer the Li⋯Li separation is short at 2.479 (8) Å. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011579/ /pubmed/21589264 http://dx.doi.org/10.1107/S1600536810046477 Text en © Han et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Hongfei
Li, Wenjuan
Li, Haoyang
Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)
title Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)
title_full Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)
title_fullStr Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)
title_full_unstemmed Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)
title_short Bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](Li—Li)
title_sort bis[μ(2)-1,1-(butane-1,4-di­yl)-2,3-dicyclo­hexyl­guanidinato]bis­[(tetra­hydro­furan)­lithium](li—li)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011579/
https://www.ncbi.nlm.nih.gov/pubmed/21589264
http://dx.doi.org/10.1107/S1600536810046477
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AT liwenjuan bism211butane14diyl23dicyclohexylguanidinatobistetrahydrofuranlithiumlili
AT lihaoyang bism211butane14diyl23dicyclohexylguanidinatobistetrahydrofuranlithiumlili

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