Pyridine-2-carboximidamidate chloride monohydrate

The title compound, C(6)H(8)N(3) (+)·Cl(−)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the –C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N—H⋯N hydrogen bonds, to...

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Detalles Bibliográficos
Autores principales: Chen, Qifan, Zhang, Huidong, Zhang, Fang, Liu, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011583/
https://www.ncbi.nlm.nih.gov/pubmed/21589465
http://dx.doi.org/10.1107/S1600536810046106
Descripción
Sumario:The title compound, C(6)H(8)N(3) (+)·Cl(−)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the –C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N—H⋯N hydrogen bonds, to chloride ions by N—H⋯Cl hydrogen bonds, and to water mol­ecules by N—H⋯O hydrogen bonds. Water mol­ecules and chloride ions are also linked together via O—H⋯Cl hydrogen bonds. In the crystal, all these inter­molecular inter­actions result in a three-dimensional network.

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