Pyridine-2-carboximidamidate chloride monohydrate

The title compound, C(6)H(8)N(3) (+)·Cl(−)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the –C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N—H⋯N hydrogen bonds, to...

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Detalles Bibliográficos
Autores principales: Chen, Qifan, Zhang, Huidong, Zhang, Fang, Liu, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011583/
https://www.ncbi.nlm.nih.gov/pubmed/21589465
http://dx.doi.org/10.1107/S1600536810046106
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author Chen, Qifan
Zhang, Huidong
Zhang, Fang
Liu, Fei
author_facet Chen, Qifan
Zhang, Huidong
Zhang, Fang
Liu, Fei
author_sort Chen, Qifan
collection PubMed
description The title compound, C(6)H(8)N(3) (+)·Cl(−)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the –C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N—H⋯N hydrogen bonds, to chloride ions by N—H⋯Cl hydrogen bonds, and to water mol­ecules by N—H⋯O hydrogen bonds. Water mol­ecules and chloride ions are also linked together via O—H⋯Cl hydrogen bonds. In the crystal, all these inter­molecular inter­actions result in a three-dimensional network.
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spelling pubmed-30115832010-12-30 Pyridine-2-carboximidamidate chloride monohydrate Chen, Qifan Zhang, Huidong Zhang, Fang Liu, Fei Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(6)H(8)N(3) (+)·Cl(−)·H(2)O, crystallizes with three formula units in the asymmetric unit. The cations are non-planar with the –C(NH(2))(2) groups twisted out of the ring planes. Each pyridine carboximidamidate cation is linked to another cation through N—H⋯N hydrogen bonds, to chloride ions by N—H⋯Cl hydrogen bonds, and to water mol­ecules by N—H⋯O hydrogen bonds. Water mol­ecules and chloride ions are also linked together via O—H⋯Cl hydrogen bonds. In the crystal, all these inter­molecular inter­actions result in a three-dimensional network. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011583/ /pubmed/21589465 http://dx.doi.org/10.1107/S1600536810046106 Text en © Chen et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Qifan
Zhang, Huidong
Zhang, Fang
Liu, Fei
Pyridine-2-carboximidamidate chloride monohydrate
title Pyridine-2-carboximidamidate chloride monohydrate
title_full Pyridine-2-carboximidamidate chloride monohydrate
title_fullStr Pyridine-2-carboximidamidate chloride monohydrate
title_full_unstemmed Pyridine-2-carboximidamidate chloride monohydrate
title_short Pyridine-2-carboximidamidate chloride monohydrate
title_sort pyridine-2-carboximidamidate chloride monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011583/
https://www.ncbi.nlm.nih.gov/pubmed/21589465
http://dx.doi.org/10.1107/S1600536810046106
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AT zhanghuidong pyridine2carboximidamidatechloridemonohydrate
AT zhangfang pyridine2carboximidamidatechloridemonohydrate
AT liufei pyridine2carboximidamidatechloridemonohydrate

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