Bis[2-(methyl­amino)­troponato]copper(II)

In the title compound, [Cu(C(8)H(8)NO)(2)], a strictly square-planar geometry about the Cu(II) metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis­(...

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Detalles Bibliográficos
Autores principales: Steyl, Gideon, Muller, Theunis J., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011584/
https://www.ncbi.nlm.nih.gov/pubmed/21589214
http://dx.doi.org/10.1107/S1600536810043503
Descripción
Sumario:In the title compound, [Cu(C(8)H(8)NO)(2)], a strictly square-planar geometry about the Cu(II) metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis­(troponato)copper(II) complex. π–π stacking is observed between the tropolone rings, with inter­planar distances of 3.5039 (16) and 3.2933 (15) Å, respectively. Additional stabilisation of the structure is accomplished through C—H⋯O hydrogen-bonding interactions.

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