Bis[2-(methyl­amino)­troponato]copper(II)

In the title compound, [Cu(C(8)H(8)NO)(2)], a strictly square-planar geometry about the Cu(II) metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis­(...

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Detalles Bibliográficos
Autores principales: Steyl, Gideon, Muller, Theunis J., Roodt, Andreas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011584/
https://www.ncbi.nlm.nih.gov/pubmed/21589214
http://dx.doi.org/10.1107/S1600536810043503
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author Steyl, Gideon
Muller, Theunis J.
Roodt, Andreas
author_facet Steyl, Gideon
Muller, Theunis J.
Roodt, Andreas
author_sort Steyl, Gideon
collection PubMed
description In the title compound, [Cu(C(8)H(8)NO)(2)], a strictly square-planar geometry about the Cu(II) metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis­(troponato)copper(II) complex. π–π stacking is observed between the tropolone rings, with inter­planar distances of 3.5039 (16) and 3.2933 (15) Å, respectively. Additional stabilisation of the structure is accomplished through C—H⋯O hydrogen-bonding interactions.
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spelling pubmed-30115842010-12-30 Bis[2-(methyl­amino)­troponato]copper(II) Steyl, Gideon Muller, Theunis J. Roodt, Andreas Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(8)H(8)NO)(2)], a strictly square-planar geometry about the Cu(II) metal atom is observed. Substitution of an O atom with a methyl-functionalized N atom does not significantly alter the bond distances and angles in the copper(II) complex when compared with a similar bis­(troponato)copper(II) complex. π–π stacking is observed between the tropolone rings, with inter­planar distances of 3.5039 (16) and 3.2933 (15) Å, respectively. Additional stabilisation of the structure is accomplished through C—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011584/ /pubmed/21589214 http://dx.doi.org/10.1107/S1600536810043503 Text en © Steyl et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Steyl, Gideon
Muller, Theunis J.
Roodt, Andreas
Bis[2-(methyl­amino)­troponato]copper(II)
title Bis[2-(methyl­amino)­troponato]copper(II)
title_full Bis[2-(methyl­amino)­troponato]copper(II)
title_fullStr Bis[2-(methyl­amino)­troponato]copper(II)
title_full_unstemmed Bis[2-(methyl­amino)­troponato]copper(II)
title_short Bis[2-(methyl­amino)­troponato]copper(II)
title_sort bis[2-(methyl­amino)­troponato]copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011584/
https://www.ncbi.nlm.nih.gov/pubmed/21589214
http://dx.doi.org/10.1107/S1600536810043503
work_keys_str_mv AT steylgideon bis2methylaminotroponatocopperii
AT mullertheunisj bis2methylaminotroponatocopperii
AT roodtandreas bis2methylaminotroponatocopperii

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