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Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2) N,O (1)}copper(II)
In the title complex, [Cu(C(14)H(14)NO(2))(2)], the discrete complex molecules have crystallographic inversion symmetry. The slightly distorted square-planar coordination sphere of the Cu(II) atom comprises two phenolate O atoms and two oxime N atoms from two bidentate–chelate 2-[1-(ethoxyimino)...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011585/ https://www.ncbi.nlm.nih.gov/pubmed/21589300 http://dx.doi.org/10.1107/S1600536810047574 |
| _version_ | 1782194977346945024 |
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| author | Dong, Wen-Kui Dong, Xiu-Yan Sun, Yin-Xia Wu, Jian-Chao Xing, Si-Jia |
| author_facet | Dong, Wen-Kui Dong, Xiu-Yan Sun, Yin-Xia Wu, Jian-Chao Xing, Si-Jia |
| author_sort | Dong, Wen-Kui |
| collection | PubMed |
| description | In the title complex, [Cu(C(14)H(14)NO(2))(2)], the discrete complex molecules have crystallographic inversion symmetry. The slightly distorted square-planar coordination sphere of the Cu(II) atom comprises two phenolate O atoms and two oxime N atoms from two bidentate–chelate 2-[1-(ethoxyimino)ethyl]-1-naphtholate O-ethyl oxime (L (−)) ligands [Cu—O = 1.8919 (17) Å and Cu—N = 1.988 (2) Å]. The two naphthalene ring systems in the molecule are parallel, with a perpendicular interplanar spacing of 1.473 (2) Å, while each complex unit forms links to four other molecules via intermolecular methyl C—H⋯π interactions, giving an infinite cross-linked layered supramolecular structure |
| format | Text |
| id | pubmed-3011585 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30115852010-12-30 Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2) N,O (1)}copper(II) Dong, Wen-Kui Dong, Xiu-Yan Sun, Yin-Xia Wu, Jian-Chao Xing, Si-Jia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(14)H(14)NO(2))(2)], the discrete complex molecules have crystallographic inversion symmetry. The slightly distorted square-planar coordination sphere of the Cu(II) atom comprises two phenolate O atoms and two oxime N atoms from two bidentate–chelate 2-[1-(ethoxyimino)ethyl]-1-naphtholate O-ethyl oxime (L (−)) ligands [Cu—O = 1.8919 (17) Å and Cu—N = 1.988 (2) Å]. The two naphthalene ring systems in the molecule are parallel, with a perpendicular interplanar spacing of 1.473 (2) Å, while each complex unit forms links to four other molecules via intermolecular methyl C—H⋯π interactions, giving an infinite cross-linked layered supramolecular structure International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011585/ /pubmed/21589300 http://dx.doi.org/10.1107/S1600536810047574 Text en © Dong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Dong, Wen-Kui Dong, Xiu-Yan Sun, Yin-Xia Wu, Jian-Chao Xing, Si-Jia Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2) N,O (1)}copper(II) |
| title | Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2)
N,O
(1)}copper(II) |
| title_full | Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2)
N,O
(1)}copper(II) |
| title_fullStr | Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2)
N,O
(1)}copper(II) |
| title_full_unstemmed | Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2)
N,O
(1)}copper(II) |
| title_short | Bis{(E)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2)
N,O
(1)}copper(II) |
| title_sort | bis{(e)-2-[1-(ethoxyimino)ethyl]-1-naphtholato-κ(2)
n,o
(1)}copper(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011585/ https://www.ncbi.nlm.nih.gov/pubmed/21589300 http://dx.doi.org/10.1107/S1600536810047574 |
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