Solvate-free bis­(triphenylphosphine)iminium chloride

The title compound, C(36)H(30)NP(2) (+)·Cl(−), crystallized in the solvate-free form from a CH(3)CN/OEt(2) solution. The chloride anion and the N atom of the [(Ph(3)P)(2)N](+) cation are located on a twofold axis, yielding overall symmetry 2 for the cation. The central P—N—P angle [133.0 (3)°] is at...

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Detalles Bibliográficos
Autores principales: Knapp, Carsten, Uzun, Rabiya
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011587/
https://www.ncbi.nlm.nih.gov/pubmed/21589480
http://dx.doi.org/10.1107/S1600536810046325
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author Knapp, Carsten
Uzun, Rabiya
author_facet Knapp, Carsten
Uzun, Rabiya
author_sort Knapp, Carsten
collection PubMed
description The title compound, C(36)H(30)NP(2) (+)·Cl(−), crystallized in the solvate-free form from a CH(3)CN/OEt(2) solution. The chloride anion and the N atom of the [(Ph(3)P)(2)N](+) cation are located on a twofold axis, yielding overall symmetry 2 for the cation. The central P—N—P angle [133.0 (3)°] is at the low end of the range of observed P—N—P angles.
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spelling pubmed-30115872010-12-30 Solvate-free bis­(triphenylphosphine)iminium chloride Knapp, Carsten Uzun, Rabiya Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(36)H(30)NP(2) (+)·Cl(−), crystallized in the solvate-free form from a CH(3)CN/OEt(2) solution. The chloride anion and the N atom of the [(Ph(3)P)(2)N](+) cation are located on a twofold axis, yielding overall symmetry 2 for the cation. The central P—N—P angle [133.0 (3)°] is at the low end of the range of observed P—N—P angles. International Union of Crystallography 2010-11-17 /pmc/articles/PMC3011587/ /pubmed/21589480 http://dx.doi.org/10.1107/S1600536810046325 Text en © Knapp and Uzun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Knapp, Carsten
Uzun, Rabiya
Solvate-free bis­(triphenylphosphine)iminium chloride
title Solvate-free bis­(triphenylphosphine)iminium chloride
title_full Solvate-free bis­(triphenylphosphine)iminium chloride
title_fullStr Solvate-free bis­(triphenylphosphine)iminium chloride
title_full_unstemmed Solvate-free bis­(triphenylphosphine)iminium chloride
title_short Solvate-free bis­(triphenylphosphine)iminium chloride
title_sort solvate-free bis­(triphenylphosphine)iminium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011587/
https://www.ncbi.nlm.nih.gov/pubmed/21589480
http://dx.doi.org/10.1107/S1600536810046325
work_keys_str_mv AT knappcarsten solvatefreebistriphenylphosphineiminiumchloride
AT uzunrabiya solvatefreebistriphenylphosphineiminiumchloride

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