1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone

The title compound, C(15)H(13)NO(2), crystallizes with four independent mol­ecules (A, B, C and D) in the asymmetric unit. The carbazole units are almost planar [maximum deviations = 0.015 (3) for A, 0.024 (3) for B, 0.026 (3) for C and 0.046 (3) Å for D]. In all four mol­ecules, there is an O—H⋯O h...

Descripción completa

Detalles Bibliográficos
Autores principales: Archana, R., Prabakaran, K., Rajendra Prasad, K. J., Thiruvalluvar, A., Butcher, R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011588/
https://www.ncbi.nlm.nih.gov/pubmed/21589445
http://dx.doi.org/10.1107/S1600536810045769
_version_ 1782194978075705344
author Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_facet Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_sort Archana, R.
collection PubMed
description The title compound, C(15)H(13)NO(2), crystallizes with four independent mol­ecules (A, B, C and D) in the asymmetric unit. The carbazole units are almost planar [maximum deviations = 0.015 (3) for A, 0.024 (3) for B, 0.026 (3) for C and 0.046 (3) Å for D]. In all four mol­ecules, there is an O—H⋯O hydrogen bond involving the hy­droxy substituent and the carbonyl O atom of the adjacent acetyl group, which forms a six-membered ring. In the crystal, the four independent mol­ecules are linked via N—H⋯O and C—H⋯O inter­actions.
format Text
id pubmed-3011588
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30115882010-12-30 1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone Archana, R. Prabakaran, K. Rajendra Prasad, K. J. Thiruvalluvar, A. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(13)NO(2), crystallizes with four independent mol­ecules (A, B, C and D) in the asymmetric unit. The carbazole units are almost planar [maximum deviations = 0.015 (3) for A, 0.024 (3) for B, 0.026 (3) for C and 0.046 (3) Å for D]. In all four mol­ecules, there is an O—H⋯O hydrogen bond involving the hy­droxy substituent and the carbonyl O atom of the adjacent acetyl group, which forms a six-membered ring. In the crystal, the four independent mol­ecules are linked via N—H⋯O and C—H⋯O inter­actions. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011588/ /pubmed/21589445 http://dx.doi.org/10.1107/S1600536810045769 Text en © Archana et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Archana, R.
Prabakaran, K.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone
title 1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone
title_full 1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone
title_fullStr 1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone
title_full_unstemmed 1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone
title_short 1-(1-Hy­droxy-8-methyl-9H-carbazol-2-yl)ethanone
title_sort 1-(1-hy­droxy-8-methyl-9h-carbazol-2-yl)ethanone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011588/
https://www.ncbi.nlm.nih.gov/pubmed/21589445
http://dx.doi.org/10.1107/S1600536810045769
work_keys_str_mv AT archanar 11hydroxy8methyl9hcarbazol2ylethanone
AT prabakarank 11hydroxy8methyl9hcarbazol2ylethanone
AT rajendraprasadkj 11hydroxy8methyl9hcarbazol2ylethanone
AT thiruvalluvara 11hydroxy8methyl9hcarbazol2ylethanone
AT butcherrj 11hydroxy8methyl9hcarbazol2ylethanone

Ejemplares similares