(2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate

The title compound, C(18)H(25)FO(9), exhibits a similar unit cell and packing to the α polymorph of axial 4a,8a-dihy­droxy­per­hydro­naph­tha­lene-2,3,6,7-tetrayl tetraacetate. The carbonyl O atoms of two of the four acetate groups in the molecule are disordered over two sites with occupancy ratios...

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Detalles Bibliográficos
Autores principales: Mehta, Goverdhan, Sen, Saikat
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011589/
https://www.ncbi.nlm.nih.gov/pubmed/21589402
http://dx.doi.org/10.1107/S1600536810044314
Descripción
Sumario:The title compound, C(18)H(25)FO(9), exhibits a similar unit cell and packing to the α polymorph of axial 4a,8a-dihy­droxy­per­hydro­naph­tha­lene-2,3,6,7-tetrayl tetraacetate. The carbonyl O atoms of two of the four acetate groups in the molecule are disordered over two sites with occupancy ratios of 0.59 (4):0.41 (4) and 0.57 (6):0.43 (6). Crystal packing is effected via inter­molecular O—H⋯O hydrogen bonds, which link the tetra­acetate mol­ecules into tapes along the c axis.

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