(2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate

The title compound, C(18)H(25)FO(9), exhibits a similar unit cell and packing to the α polymorph of axial 4a,8a-dihy­droxy­per­hydro­naph­tha­lene-2,3,6,7-tetrayl tetraacetate. The carbonyl O atoms of two of the four acetate groups in the molecule are disordered over two sites with occupancy ratios...

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Detalles Bibliográficos
Autores principales: Mehta, Goverdhan, Sen, Saikat
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011589/
https://www.ncbi.nlm.nih.gov/pubmed/21589402
http://dx.doi.org/10.1107/S1600536810044314
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author Mehta, Goverdhan
Sen, Saikat
author_facet Mehta, Goverdhan
Sen, Saikat
author_sort Mehta, Goverdhan
collection PubMed
description The title compound, C(18)H(25)FO(9), exhibits a similar unit cell and packing to the α polymorph of axial 4a,8a-dihy­droxy­per­hydro­naph­tha­lene-2,3,6,7-tetrayl tetraacetate. The carbonyl O atoms of two of the four acetate groups in the molecule are disordered over two sites with occupancy ratios of 0.59 (4):0.41 (4) and 0.57 (6):0.43 (6). Crystal packing is effected via inter­molecular O—H⋯O hydrogen bonds, which link the tetra­acetate mol­ecules into tapes along the c axis.
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spelling pubmed-30115892010-12-30 (2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate Mehta, Goverdhan Sen, Saikat Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(25)FO(9), exhibits a similar unit cell and packing to the α polymorph of axial 4a,8a-dihy­droxy­per­hydro­naph­tha­lene-2,3,6,7-tetrayl tetraacetate. The carbonyl O atoms of two of the four acetate groups in the molecule are disordered over two sites with occupancy ratios of 0.59 (4):0.41 (4) and 0.57 (6):0.43 (6). Crystal packing is effected via inter­molecular O—H⋯O hydrogen bonds, which link the tetra­acetate mol­ecules into tapes along the c axis. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011589/ /pubmed/21589402 http://dx.doi.org/10.1107/S1600536810044314 Text en © Mehta and Sen 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mehta, Goverdhan
Sen, Saikat
(2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate
title (2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate
title_full (2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate
title_fullStr (2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate
title_full_unstemmed (2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate
title_short (2R,3R,4aS,6S,7S,8aS)-4a-Fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate
title_sort (2r,3r,4as,6s,7s,8as)-4a-fluoro-8a-hy­droxy­perhydro­naphthalene-2,3,6,7-tetrayl tetraacetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011589/
https://www.ncbi.nlm.nih.gov/pubmed/21589402
http://dx.doi.org/10.1107/S1600536810044314
work_keys_str_mv AT mehtagoverdhan 2r3r4as6s7s8as4afluoro8ahydroxyperhydronaphthalene2367tetrayltetraacetate
AT sensaikat 2r3r4as6s7s8as4afluoro8ahydroxyperhydronaphthalene2367tetrayltetraacetate

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