Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate

The asymmetric unit of the title compound, C(10)H(13)NO(3), contains two crystallographically independent mol­ecules with different conformations of the eth­oxy­carbonyl groups; the terminal C—C—O—C torsion angles in the two mol­ecules are 83.6 (6) and −171.1 (3)°, resulting in twisted and straight...

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Detalles Bibliográficos
Autores principales: Zhang, Fang, Liang, Wen-De, Li, Gong-Xing, Jiang, Wang, Xiao, Zhu-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011596/
https://www.ncbi.nlm.nih.gov/pubmed/21589379
http://dx.doi.org/10.1107/S1600536810044399
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author Zhang, Fang
Liang, Wen-De
Li, Gong-Xing
Jiang, Wang
Xiao, Zhu-Ping
author_facet Zhang, Fang
Liang, Wen-De
Li, Gong-Xing
Jiang, Wang
Xiao, Zhu-Ping
author_sort Zhang, Fang
collection PubMed
description The asymmetric unit of the title compound, C(10)H(13)NO(3), contains two crystallographically independent mol­ecules with different conformations of the eth­oxy­carbonyl groups; the terminal C—C—O—C torsion angles in the two mol­ecules are 83.6 (6) and −171.1 (3)°, resulting in twisted and straight chain conformations, respectively. The crystal structure is stabilized by inter­molecular N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. Intra­molecular hydrogen bonds occur between the amino N and phenolic O atoms.
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spelling pubmed-30115962010-12-30 Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate Zhang, Fang Liang, Wen-De Li, Gong-Xing Jiang, Wang Xiao, Zhu-Ping Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(13)NO(3), contains two crystallographically independent mol­ecules with different conformations of the eth­oxy­carbonyl groups; the terminal C—C—O—C torsion angles in the two mol­ecules are 83.6 (6) and −171.1 (3)°, resulting in twisted and straight chain conformations, respectively. The crystal structure is stabilized by inter­molecular N—H⋯O, O—H⋯N and C—H⋯O hydrogen bonds. Intra­molecular hydrogen bonds occur between the amino N and phenolic O atoms. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011596/ /pubmed/21589379 http://dx.doi.org/10.1107/S1600536810044399 Text en © Zhang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Fang
Liang, Wen-De
Li, Gong-Xing
Jiang, Wang
Xiao, Zhu-Ping
Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate
title Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate
title_full Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate
title_fullStr Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate
title_full_unstemmed Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate
title_short Ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate
title_sort ethyl 2-(3-amino-4-hy­droxy­phen­yl)acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011596/
https://www.ncbi.nlm.nih.gov/pubmed/21589379
http://dx.doi.org/10.1107/S1600536810044399
work_keys_str_mv AT zhangfang ethyl23amino4hydroxyphenylacetate
AT liangwende ethyl23amino4hydroxyphenylacetate
AT ligongxing ethyl23amino4hydroxyphenylacetate
AT jiangwang ethyl23amino4hydroxyphenylacetate
AT xiaozhuping ethyl23amino4hydroxyphenylacetate

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