Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]]

In the coordination polymer, {(C(2)H(8)N)[Cd(CHO(2))(3)]}(n), the Cd(II) atom lies on a special position of [Image: see text] site symmetry in an octa­hedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the...

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Detalles Bibliográficos
Autores principales: Gao, Shan, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011599/
https://www.ncbi.nlm.nih.gov/pubmed/21589281
http://dx.doi.org/10.1107/S1600536810046830
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author Gao, Shan
Ng, Seik Weng
author_facet Gao, Shan
Ng, Seik Weng
author_sort Gao, Shan
collection PubMed
description In the coordination polymer, {(C(2)H(8)N)[Cd(CHO(2))(3)]}(n), the Cd(II) atom lies on a special position of [Image: see text] site symmetry in an octa­hedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the cavities within the framework, and are N—H⋯O hydrogen-bonded to the framework.
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spelling pubmed-30115992010-12-30 Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]] Gao, Shan Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the coordination polymer, {(C(2)H(8)N)[Cd(CHO(2))(3)]}(n), the Cd(II) atom lies on a special position of [Image: see text] site symmetry in an octa­hedron of O atoms. The formate unit bridges the metal atoms, generating a three-dimensional polyanionic framework. The disordered cations occupy the cavities within the framework, and are N—H⋯O hydrogen-bonded to the framework. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011599/ /pubmed/21589281 http://dx.doi.org/10.1107/S1600536810046830 Text en © Gao and Ng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Shan
Ng, Seik Weng
Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]]
title Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]]
title_full Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]]
title_fullStr Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]]
title_full_unstemmed Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]]
title_short Poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) O:O′)cadmate(II)]]
title_sort poly[dimethyl­ammonium [tris­(μ(2)-formato-κ(2) o:o′)cadmate(ii)]]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011599/
https://www.ncbi.nlm.nih.gov/pubmed/21589281
http://dx.doi.org/10.1107/S1600536810046830
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AT ngseikweng polydimethylammoniumtrism2formatok2oocadmateii

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