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catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-pentanedioato] monohydrate]
In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a...
Autor principal: | |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011601/ https://www.ncbi.nlm.nih.gov/pubmed/21589224 http://dx.doi.org/10.1107/S1600536810042340 |
Sumario: | In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a distorted cis-ZnN(2)O(4) octahedral coordination geometry for the metal ion. The bridging glu species generates [110] polymeric chains in the crystal. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water molecules help to consolidate the structure and neighbouring pyphen units interact through numerous aromatic π–π interactions [minimum centroid–centroid separation = 3.654 (3) Å], resulting in a two-dimensional network. |
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