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catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-pentanedioato] monohydrate]
In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011601/ https://www.ncbi.nlm.nih.gov/pubmed/21589224 http://dx.doi.org/10.1107/S1600536810042340 |
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author | Fang, Wei |
author_facet | Fang, Wei |
author_sort | Fang, Wei |
collection | PubMed |
description | In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a distorted cis-ZnN(2)O(4) octahedral coordination geometry for the metal ion. The bridging glu species generates [110] polymeric chains in the crystal. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water molecules help to consolidate the structure and neighbouring pyphen units interact through numerous aromatic π–π interactions [minimum centroid–centroid separation = 3.654 (3) Å], resulting in a two-dimensional network. |
format | Text |
id | pubmed-3011601 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116012010-12-30 catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-pentanedioato] monohydrate] Fang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a distorted cis-ZnN(2)O(4) octahedral coordination geometry for the metal ion. The bridging glu species generates [110] polymeric chains in the crystal. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water molecules help to consolidate the structure and neighbouring pyphen units interact through numerous aromatic π–π interactions [minimum centroid–centroid separation = 3.654 (3) Å], resulting in a two-dimensional network. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011601/ /pubmed/21589224 http://dx.doi.org/10.1107/S1600536810042340 Text en © Wei Fang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fang, Wei catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-pentanedioato] monohydrate] |
title |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2)
N
(8),N
(9))zinc(II)]-μ-pentanedioato] monohydrate] |
title_full |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2)
N
(8),N
(9))zinc(II)]-μ-pentanedioato] monohydrate] |
title_fullStr |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2)
N
(8),N
(9))zinc(II)]-μ-pentanedioato] monohydrate] |
title_full_unstemmed |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2)
N
(8),N
(9))zinc(II)]-μ-pentanedioato] monohydrate] |
title_short |
catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2)
N
(8),N
(9))zinc(II)]-μ-pentanedioato] monohydrate] |
title_sort | catena-poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline-κ(2)
n
(8),n
(9))zinc(ii)]-μ-pentanedioato] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011601/ https://www.ncbi.nlm.nih.gov/pubmed/21589224 http://dx.doi.org/10.1107/S1600536810042340 |
work_keys_str_mv | AT fangwei catenapolyaquapyrazino23f110phenanthrolinek2n8n9zinciimpentanedioatomonohydrate |