Cargando…

catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate]

In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino­[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a...

Descripción completa

Detalles Bibliográficos
Autor principal: Fang, Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011601/
https://www.ncbi.nlm.nih.gov/pubmed/21589224
http://dx.doi.org/10.1107/S1600536810042340
_version_ 1782194981238210560
author Fang, Wei
author_facet Fang, Wei
author_sort Fang, Wei
collection PubMed
description In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino­[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a distorted cis-ZnN(2)O(4) octa­hedral coordination geometry for the metal ion. The bridging glu species generates [110] polymeric chains in the crystal. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water mol­ecules help to consolidate the structure and neighbouring pyphen units inter­act through numerous aromatic π–π inter­actions [minimum centroid–centroid separation = 3.654 (3) Å], resulting in a two-dimensional network.
format Text
id pubmed-3011601
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30116012010-12-30 catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate] Fang, Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(5)H(6)O(4))(C(14)H(8)N(4))(H(2)O)]·H(2)O}(n), the Zn(2+) ion is coordinated by an N,N′-bidentate pyrazino­[2,3-f][1,10]phenanthroline (pyphen) ligand, a water molecule and a monodentate glutarate (glu) dianion. A symmetry-generated O:O′-bidentate glu dianion completes a distorted cis-ZnN(2)O(4) octa­hedral coordination geometry for the metal ion. The bridging glu species generates [110] polymeric chains in the crystal. O—H⋯O hydrogen bonds involving both the coordinated and uncoordinated water mol­ecules help to consolidate the structure and neighbouring pyphen units inter­act through numerous aromatic π–π inter­actions [minimum centroid–centroid separation = 3.654 (3) Å], resulting in a two-dimensional network. International Union of Crystallography 2010-11-06 /pmc/articles/PMC3011601/ /pubmed/21589224 http://dx.doi.org/10.1107/S1600536810042340 Text en © Wei Fang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fang, Wei
catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate]
title catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate]
title_full catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate]
title_fullStr catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate]
title_full_unstemmed catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate]
title_short catena-Poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) N (8),N (9))zinc(II)]-μ-penta­nedioato] monohydrate]
title_sort catena-poly[[[aqua­(pyrazino­[2,3-f][1,10]phenanthroline-κ(2) n (8),n (9))zinc(ii)]-μ-penta­nedioato] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011601/
https://www.ncbi.nlm.nih.gov/pubmed/21589224
http://dx.doi.org/10.1107/S1600536810042340
work_keys_str_mv AT fangwei catenapolyaquapyrazino23f110phenanthrolinek2n8n9zinciimpentanedioatomonohydrate