(1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne

The title compound, C(16)H(24)Cl(2)O, was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (cedrus atlantica). The mol­ecule forms an extended sheet of two fused rings which exhibit diffe...

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Detalles Bibliográficos
Autores principales: Benharref, Ahmed, El Ammari, Lahcen, Avignant, Daniel, Oudahmane, Abdelghani, Berraho, Moha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011603/
https://www.ncbi.nlm.nih.gov/pubmed/21589429
http://dx.doi.org/10.1107/S1600536810045344
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author Benharref, Ahmed
El Ammari, Lahcen
Avignant, Daniel
Oudahmane, Abdelghani
Berraho, Moha
author_facet Benharref, Ahmed
El Ammari, Lahcen
Avignant, Daniel
Oudahmane, Abdelghani
Berraho, Moha
author_sort Benharref, Ahmed
collection PubMed
description The title compound, C(16)H(24)Cl(2)O, was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (cedrus atlantica). The mol­ecule forms an extended sheet of two fused rings which exhibit different conformations. The six-membered ring has a half-chair conformation, while the seven-membered ring displays a chair conformation; the dihedral angle between the two rings is 38.2 (1)°.
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spelling pubmed-30116032010-12-30 (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne Benharref, Ahmed El Ammari, Lahcen Avignant, Daniel Oudahmane, Abdelghani Berraho, Moha Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(24)Cl(2)O, was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (cedrus atlantica). The mol­ecule forms an extended sheet of two fused rings which exhibit different conformations. The six-membered ring has a half-chair conformation, while the seven-membered ring displays a chair conformation; the dihedral angle between the two rings is 38.2 (1)°. International Union of Crystallography 2010-11-10 /pmc/articles/PMC3011603/ /pubmed/21589429 http://dx.doi.org/10.1107/S1600536810045344 Text en © Benharref et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Benharref, Ahmed
El Ammari, Lahcen
Avignant, Daniel
Oudahmane, Abdelghani
Berraho, Moha
(1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne
title (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne
title_full (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne
title_fullStr (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne
title_full_unstemmed (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne
title_short (1S,3R,8S,9R,10S)-2,2-Dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne
title_sort (1s,3r,8s,9r,10s)-2,2-dichloro-3,7,7,10-tetra­methyl-9,10-ep­oxy­tricyclo­[6.4.0.0(1,3)]dodeca­ne
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011603/
https://www.ncbi.nlm.nih.gov/pubmed/21589429
http://dx.doi.org/10.1107/S1600536810045344
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