trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)bis­(nitrato-κ(2) O,O′)zinc(II)

The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn—O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C (2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diph...

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Detalles Bibliográficos
Autores principales: Fernandes, José A., Almeida Paz, Filipe A., Liu, Feng-Yi, Cunha-Silva, Luís, Carlos, Luís D., Rocha, João
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011604/
https://www.ncbi.nlm.nih.gov/pubmed/21589287
http://dx.doi.org/10.1107/S1600536810047161
Descripción
Sumario:The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn—O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C (2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a complex with an overall coordination number of 8 for the metal ion.

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