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trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)bis(nitrato-κ(2) O,O′)zinc(II)
The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn—O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C (2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diph...
| Autores principales: | , , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011604/ https://www.ncbi.nlm.nih.gov/pubmed/21589287 http://dx.doi.org/10.1107/S1600536810047161 |
| _version_ | 1782194981963825152 |
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| author | Fernandes, José A. Almeida Paz, Filipe A. Liu, Feng-Yi Cunha-Silva, Luís Carlos, Luís D. Rocha, João |
| author_facet | Fernandes, José A. Almeida Paz, Filipe A. Liu, Feng-Yi Cunha-Silva, Luís Carlos, Luís D. Rocha, João |
| author_sort | Fernandes, José A. |
| collection | PubMed |
| description | The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn—O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C (2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a complex with an overall coordination number of 8 for the metal ion. |
| format | Text |
| id | pubmed-3011604 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30116042010-12-30 trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)bis(nitrato-κ(2) O,O′)zinc(II) Fernandes, José A. Almeida Paz, Filipe A. Liu, Feng-Yi Cunha-Silva, Luís Carlos, Luís D. Rocha, João Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(NO(3))(2)(C(24)H(16)N(2))(2)], is a twofold axially symmetric coordination compound. Given that the Zn—O interactions [2.4926 (15) and 2.6673 (15) Å] can be considered as weakly bonding and the nitrate ions share the same C (2) axis of the Zn(dpp)(2) fragment (dpp is 4,7-diphenyl-1,10-phenanthroline), these anions belong to the coordination sphere of Zn(2+), leading to a complex with an overall coordination number of 8 for the metal ion. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011604/ /pubmed/21589287 http://dx.doi.org/10.1107/S1600536810047161 Text en © Fernandes et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fernandes, José A. Almeida Paz, Filipe A. Liu, Feng-Yi Cunha-Silva, Luís Carlos, Luís D. Rocha, João trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2) N,N′)bis(nitrato-κ(2) O,O′)zinc(II) |
| title |
trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)zinc(II) |
| title_full |
trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)zinc(II) |
| title_fullStr |
trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)zinc(II) |
| title_full_unstemmed |
trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)zinc(II) |
| title_short |
trans-Bis(4,7-diphenyl-1,10-phenanthroline-κ(2)
N,N′)bis(nitrato-κ(2)
O,O′)zinc(II) |
| title_sort | trans-bis(4,7-diphenyl-1,10-phenanthroline-κ(2)
n,n′)bis(nitrato-κ(2)
o,o′)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011604/ https://www.ncbi.nlm.nih.gov/pubmed/21589287 http://dx.doi.org/10.1107/S1600536810047161 |
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