[μ-1,3-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))propan-2-olato-κ(2) O:O]bis­[(ethanol-κO)zinc(II)] bis­(perchlorate)

In the centrosymmetric dinuclear title complex, [Zn(2)(C(13)H(19)N(4)O)(2)(C(2)H(5)OH)(2)](ClO(4))(2), the Zn(II) atom is in a distorted trigonal-bipyramidal coordination geometry. The equatorial plane is constructed by one N atom and one O atom from two 1,3-bis­(3,5-dimethyl­pyrazol-1-yl)propan-2-o...

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Detalles Bibliográficos
Autores principales: Tian, Da-Min, Shi, Chong-Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011605/
https://www.ncbi.nlm.nih.gov/pubmed/21589222
http://dx.doi.org/10.1107/S160053681004479X
Descripción
Sumario:In the centrosymmetric dinuclear title complex, [Zn(2)(C(13)H(19)N(4)O)(2)(C(2)H(5)OH)(2)](ClO(4))(2), the Zn(II) atom is in a distorted trigonal-bipyramidal coordination geometry. The equatorial plane is constructed by one N atom and one O atom from two 1,3-bis­(3,5-dimethyl­pyrazol-1-yl)propan-2-olate (bppo) ligands and one O atom from an ethanol mol­ecule. One N atom and one O atom from the two bppo ligands occupy the axial positions. Inter­molecular O—H⋯O hydrogen bonds between the ethanol mol­ecules and perchlorate anions, and O⋯π inter­actions between the perchlorate anions and pyrazole rings [O⋯centroid distances = 3.494 (3) and 3.413 (3) Å], lead to a chain structure along [010].

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