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Diaquadichloridobis[quinazolin-4(1H)-one-κN (3)]copper(II)
In the title complex, [CuCl(2)(C(8)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) ion is located on an inversion center and is octahedrally coordinated by two N atoms of the 1H-quinazolin-4-one ligand, two chloride ligands and two aqua ligands. The axial Cu—O distances are significantly longer [2.512 (2) Å],...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011606/ https://www.ncbi.nlm.nih.gov/pubmed/21589337 http://dx.doi.org/10.1107/S1600536810048890 |
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author | Turgunov, Kambarali Shomurotova, Shirin Mukhamedov, Nasir Tashkhodjaev, Bakhodir |
author_facet | Turgunov, Kambarali Shomurotova, Shirin Mukhamedov, Nasir Tashkhodjaev, Bakhodir |
author_sort | Turgunov, Kambarali |
collection | PubMed |
description | In the title complex, [CuCl(2)(C(8)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) ion is located on an inversion center and is octahedrally coordinated by two N atoms of the 1H-quinazolin-4-one ligand, two chloride ligands and two aqua ligands. The axial Cu—O distances are significantly longer [2.512 (2) Å], than the Cu—N [2.022 (2) Å] and Cu—Cl [2.3232 (4) Å] distances as a result of Jahn–Teller distortion. Aqua ligands are involved in intra- and intermolecular hydrogen bonding, and N—H⋯O intermolecular hydrogen bonds are formed between the organic ligands. In addition, weak π–π interactions are observed between the benzene rings of the ligand [centroid–centroid distance = 3.678 (1) Å]. |
format | Text |
id | pubmed-3011606 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116062010-12-30 Diaquadichloridobis[quinazolin-4(1H)-one-κN (3)]copper(II) Turgunov, Kambarali Shomurotova, Shirin Mukhamedov, Nasir Tashkhodjaev, Bakhodir Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CuCl(2)(C(8)H(6)N(2)O)(2)(H(2)O)(2)], the Cu(II) ion is located on an inversion center and is octahedrally coordinated by two N atoms of the 1H-quinazolin-4-one ligand, two chloride ligands and two aqua ligands. The axial Cu—O distances are significantly longer [2.512 (2) Å], than the Cu—N [2.022 (2) Å] and Cu—Cl [2.3232 (4) Å] distances as a result of Jahn–Teller distortion. Aqua ligands are involved in intra- and intermolecular hydrogen bonding, and N—H⋯O intermolecular hydrogen bonds are formed between the organic ligands. In addition, weak π–π interactions are observed between the benzene rings of the ligand [centroid–centroid distance = 3.678 (1) Å]. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011606/ /pubmed/21589337 http://dx.doi.org/10.1107/S1600536810048890 Text en © Turgunov et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Turgunov, Kambarali Shomurotova, Shirin Mukhamedov, Nasir Tashkhodjaev, Bakhodir Diaquadichloridobis[quinazolin-4(1H)-one-κN (3)]copper(II) |
title | Diaquadichloridobis[quinazolin-4(1H)-one-κN
(3)]copper(II) |
title_full | Diaquadichloridobis[quinazolin-4(1H)-one-κN
(3)]copper(II) |
title_fullStr | Diaquadichloridobis[quinazolin-4(1H)-one-κN
(3)]copper(II) |
title_full_unstemmed | Diaquadichloridobis[quinazolin-4(1H)-one-κN
(3)]copper(II) |
title_short | Diaquadichloridobis[quinazolin-4(1H)-one-κN
(3)]copper(II) |
title_sort | diaquadichloridobis[quinazolin-4(1h)-one-κn
(3)]copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011606/ https://www.ncbi.nlm.nih.gov/pubmed/21589337 http://dx.doi.org/10.1107/S1600536810048890 |
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