Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]

In the title complex, [CdCl(2)(C(4)H(8)O(2))](n), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa­hedral geometry and is co...

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Detalles Bibliográficos
Autores principales: Wang, Jian-Qiang, Du, Ren-Jun, Wang, Wei, Luan, Chang-Jun, Guo, Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011614/
https://www.ncbi.nlm.nih.gov/pubmed/21589339
http://dx.doi.org/10.1107/S1600536810048634
Descripción
Sumario:In the title complex, [CdCl(2)(C(4)H(8)O(2))](n), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa­hedral geometry and is connected to neighboring Cd(II) ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further inter­connected by bridging 1,4-dioxane ligands, affording a three-dimensional network.

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