Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]

In the title complex, [CdCl(2)(C(4)H(8)O(2))](n), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa­hedral geometry and is co...

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Detalles Bibliográficos
Autores principales: Wang, Jian-Qiang, Du, Ren-Jun, Wang, Wei, Luan, Chang-Jun, Guo, Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011614/
https://www.ncbi.nlm.nih.gov/pubmed/21589339
http://dx.doi.org/10.1107/S1600536810048634
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author Wang, Jian-Qiang
Du, Ren-Jun
Wang, Wei
Luan, Chang-Jun
Guo, Cheng
author_facet Wang, Jian-Qiang
Du, Ren-Jun
Wang, Wei
Luan, Chang-Jun
Guo, Cheng
author_sort Wang, Jian-Qiang
collection PubMed
description In the title complex, [CdCl(2)(C(4)H(8)O(2))](n), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa­hedral geometry and is connected to neighboring Cd(II) ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further inter­connected by bridging 1,4-dioxane ligands, affording a three-dimensional network.
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spelling pubmed-30116142010-12-30 Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)] Wang, Jian-Qiang Du, Ren-Jun Wang, Wei Luan, Chang-Jun Guo, Cheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [CdCl(2)(C(4)H(8)O(2))](n), two different Cd(II) ions are present, one in a general position and one with site symmetry 2. The Cd(II) ions are coordinated by two O atoms from two 1,4-dioxane ligands and four chloride anions in a slightly distorted octa­hedral geometry and is connected to neighboring Cd(II) ions by two bridging chloride anions, generating infinite linear chains along the a axis. These chains are further inter­connected by bridging 1,4-dioxane ligands, affording a three-dimensional network. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011614/ /pubmed/21589339 http://dx.doi.org/10.1107/S1600536810048634 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Jian-Qiang
Du, Ren-Jun
Wang, Wei
Luan, Chang-Jun
Guo, Cheng
Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]
title Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]
title_full Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]
title_fullStr Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]
title_full_unstemmed Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]
title_short Poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) O:O′)-cadmium(II)]
title_sort poly[di-μ(2)-chlorido-μ(2)-(1,4-dioxane-κ(2) o:o′)-cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011614/
https://www.ncbi.nlm.nih.gov/pubmed/21589339
http://dx.doi.org/10.1107/S1600536810048634
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AT guocheng polydim2chloridom214dioxanek2oocadmiumii

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