Chlorido{2-[(dimethyl­amino)­methyl]phenyl-κ(2) C (1),N}(1-methyl-1H-imidazole-κN (3))palladium(II)

In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methyl­imidazole with dimeric dichloridobis[2-(dimethyl­amino)­benz­yl]palla­dium(II), the ring-deprotonated N,N-dimethyl­benzyl­amine ligand acts in a C,N-bidentate fashion. The dihedral angle betw...

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Detalles Bibliográficos
Autores principales: Clements, Jason W., Stojanovic, Milorad, Hoffman, Norris W., Sykora, Richard E.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011615/
https://www.ncbi.nlm.nih.gov/pubmed/21589311
http://dx.doi.org/10.1107/S1600536810047367
Descripción
Sumario:In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methyl­imidazole with dimeric dichloridobis[2-(dimethyl­amino)­benz­yl]palla­dium(II), the ring-deprotonated N,N-dimethyl­benzyl­amine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methyl­imidazole ligand and the palladacycle plane is 57.88 (16)°. The two N atoms from the N,N-dimethyl­benzyl­amine and 1-methyl­imidazole ligands are trans coordinated to the Pd(II) atom.

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