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Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2) C (1),N}(1-methyl-1H-imidazole-κN (3))palladium(II)
In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methylimidazole with dimeric dichloridobis[2-(dimethylamino)benzyl]palladium(II), the ring-deprotonated N,N-dimethylbenzylamine ligand acts in a C,N-bidentate fashion. The dihedral angle betw...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011615/ https://www.ncbi.nlm.nih.gov/pubmed/21589311 http://dx.doi.org/10.1107/S1600536810047367 |
| _version_ | 1782194984742551552 |
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| author | Clements, Jason W. Stojanovic, Milorad Hoffman, Norris W. Sykora, Richard E. |
| author_facet | Clements, Jason W. Stojanovic, Milorad Hoffman, Norris W. Sykora, Richard E. |
| author_sort | Clements, Jason W. |
| collection | PubMed |
| description | In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methylimidazole with dimeric dichloridobis[2-(dimethylamino)benzyl]palladium(II), the ring-deprotonated N,N-dimethylbenzylamine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methylimidazole ligand and the palladacycle plane is 57.88 (16)°. The two N atoms from the N,N-dimethylbenzylamine and 1-methylimidazole ligands are trans coordinated to the Pd(II) atom. |
| format | Text |
| id | pubmed-3011615 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30116152010-12-30 Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2) C (1),N}(1-methyl-1H-imidazole-κN (3))palladium(II) Clements, Jason W. Stojanovic, Milorad Hoffman, Norris W. Sykora, Richard E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methylimidazole with dimeric dichloridobis[2-(dimethylamino)benzyl]palladium(II), the ring-deprotonated N,N-dimethylbenzylamine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methylimidazole ligand and the palladacycle plane is 57.88 (16)°. The two N atoms from the N,N-dimethylbenzylamine and 1-methylimidazole ligands are trans coordinated to the Pd(II) atom. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011615/ /pubmed/21589311 http://dx.doi.org/10.1107/S1600536810047367 Text en © Clements et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Clements, Jason W. Stojanovic, Milorad Hoffman, Norris W. Sykora, Richard E. Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2) C (1),N}(1-methyl-1H-imidazole-κN (3))palladium(II) |
| title | Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2)
C
(1),N}(1-methyl-1H-imidazole-κN
(3))palladium(II) |
| title_full | Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2)
C
(1),N}(1-methyl-1H-imidazole-κN
(3))palladium(II) |
| title_fullStr | Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2)
C
(1),N}(1-methyl-1H-imidazole-κN
(3))palladium(II) |
| title_full_unstemmed | Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2)
C
(1),N}(1-methyl-1H-imidazole-κN
(3))palladium(II) |
| title_short | Chlorido{2-[(dimethylamino)methyl]phenyl-κ(2)
C
(1),N}(1-methyl-1H-imidazole-κN
(3))palladium(II) |
| title_sort | chlorido{2-[(dimethylamino)methyl]phenyl-κ(2)
c
(1),n}(1-methyl-1h-imidazole-κn
(3))palladium(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011615/ https://www.ncbi.nlm.nih.gov/pubmed/21589311 http://dx.doi.org/10.1107/S1600536810047367 |
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