Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate

The structure of the title compound, C(16)H(19)N(3)O(4)S, shows the planes described by the thio­phene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip [occupancy ratio...

Descripción completa

Detalles Bibliográficos
Autores principales: Dufresne, Stéphane, Skene, W. G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011617/
https://www.ncbi.nlm.nih.gov/pubmed/21589512
http://dx.doi.org/10.1107/S1600536810046775
_version_ 1782194985224896512
author Dufresne, Stéphane
Skene, W. G.
author_facet Dufresne, Stéphane
Skene, W. G.
author_sort Dufresne, Stéphane
collection PubMed
description The structure of the title compound, C(16)H(19)N(3)O(4)S, shows the planes described by the thio­phene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip [occupancy ratio 0.729 (5):0.271 (5)]. The three-dimensional network is well packed and involves N–H⋯O hydrogen bonding and π–π stacking [centroid–centroid distance = 4.294 (8) Å].
format Text
id pubmed-3011617
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30116172010-12-30 Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate Dufresne, Stéphane Skene, W. G. Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title compound, C(16)H(19)N(3)O(4)S, shows the planes described by the thio­phene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip [occupancy ratio 0.729 (5):0.271 (5)]. The three-dimensional network is well packed and involves N–H⋯O hydrogen bonding and π–π stacking [centroid–centroid distance = 4.294 (8) Å]. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011617/ /pubmed/21589512 http://dx.doi.org/10.1107/S1600536810046775 Text en © Dufresne and Skene 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dufresne, Stéphane
Skene, W. G.
Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
title Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
title_full Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
title_fullStr Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
title_full_unstemmed Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
title_short Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
title_sort diethyl 2-amino-5-[(e)-(1-methyl-1h-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011617/
https://www.ncbi.nlm.nih.gov/pubmed/21589512
http://dx.doi.org/10.1107/S1600536810046775
work_keys_str_mv AT dufresnestephane diethyl2amino5e1methyl1hpyrrol2ylmethylideneaminothiophene34dicarboxylate
AT skenewg diethyl2amino5e1methyl1hpyrrol2ylmethylideneaminothiophene34dicarboxylate

Ejemplares similares