(S)-3-Bromo-4-diallyl­amino-5-[(1R,2S,5R)-2-isopropyl-5-methyl­cyclo­hex­yloxy]furan-2(5H)-one

The title compound, C(20)H(30)BrNO(3), was obtained via a tandem asymmetric Michael addition–elimination reaction of 3,4-dibromo-5-(S)-(l-menth­yloxy)-2(5H)-furan­one and diallyl­amine in the presence of potassium fluoride. In the mol­ecule, the five-membered furan­one ring is approximately planar [...

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Detalles Bibliográficos
Autores principales: Fu, Jian-Hua, Wang, Zhao-Yang, Li, Jian-Xiao, Tan, Yue-He
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011618/
https://www.ncbi.nlm.nih.gov/pubmed/21589558
http://dx.doi.org/10.1107/S1600536810047173
Descripción
Sumario:The title compound, C(20)H(30)BrNO(3), was obtained via a tandem asymmetric Michael addition–elimination reaction of 3,4-dibromo-5-(S)-(l-menth­yloxy)-2(5H)-furan­one and diallyl­amine in the presence of potassium fluoride. In the mol­ecule, the five-membered furan­one ring is approximately planar [maximum atomic deviation = 0.030 (3) Å], and the six-membered cyclo­hexane ring adopts a chair conformation.

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