Cargando…
Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate
In the title compound, [PtCl(C(27)H(35)N(3))]BF(4), the Pt(II) atom is in a pseudo-square-planar coordination, which is typical of Pt–terpyridine complexes. The Pt—Cl bond distance is 2.2998 (7) Å. The Pt—N distance of the N atom on the central pyridine is 1.931 (2) Å, while the peripheral N atoms h...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011620/ https://www.ncbi.nlm.nih.gov/pubmed/21589353 http://dx.doi.org/10.1107/S1600536810048762 |
_version_ | 1782194985956802560 |
---|---|
author | Batrice, Rami J. Nesterov, Vladimir N. Smucker, Bradley W. |
author_facet | Batrice, Rami J. Nesterov, Vladimir N. Smucker, Bradley W. |
author_sort | Batrice, Rami J. |
collection | PubMed |
description | In the title compound, [PtCl(C(27)H(35)N(3))]BF(4), the Pt(II) atom is in a pseudo-square-planar coordination, which is typical of Pt–terpyridine complexes. The Pt—Cl bond distance is 2.2998 (7) Å. The Pt—N distance of the N atom on the central pyridine is 1.931 (2) Å, while the peripheral N atoms have Pt—N distances of 2.018 (2) and 2.022 (2) Å. The cations pack as dimers in a head-to-tail orientation with an intermolecular Pt⋯Pt distance of 3.5214 (2) Å and Pt⋯N distances of 3.527 (2), 3.873 (2) and 4.532 (2) Å. In the crystal, cations and anions are linked by weak C—H⋯F hydrogen-bonding interactions. |
format | Text |
id | pubmed-3011620 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116202010-12-30 Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate Batrice, Rami J. Nesterov, Vladimir N. Smucker, Bradley W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PtCl(C(27)H(35)N(3))]BF(4), the Pt(II) atom is in a pseudo-square-planar coordination, which is typical of Pt–terpyridine complexes. The Pt—Cl bond distance is 2.2998 (7) Å. The Pt—N distance of the N atom on the central pyridine is 1.931 (2) Å, while the peripheral N atoms have Pt—N distances of 2.018 (2) and 2.022 (2) Å. The cations pack as dimers in a head-to-tail orientation with an intermolecular Pt⋯Pt distance of 3.5214 (2) Å and Pt⋯N distances of 3.527 (2), 3.873 (2) and 4.532 (2) Å. In the crystal, cations and anions are linked by weak C—H⋯F hydrogen-bonding interactions. International Union of Crystallography 2010-11-30 /pmc/articles/PMC3011620/ /pubmed/21589353 http://dx.doi.org/10.1107/S1600536810048762 Text en © Batrice et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Batrice, Rami J. Nesterov, Vladimir N. Smucker, Bradley W. Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate |
title | Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate |
title_full | Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate |
title_fullStr | Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate |
title_full_unstemmed | Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate |
title_short | Chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(II) tetrafluoridoborate |
title_sort | chlorido(4,4′,4′′-tri-tert-butyl-2,2′:6′,2′′-terpyridine)platinum(ii) tetrafluoridoborate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011620/ https://www.ncbi.nlm.nih.gov/pubmed/21589353 http://dx.doi.org/10.1107/S1600536810048762 |
work_keys_str_mv | AT batriceramij chlorido444tritertbutyl2262terpyridineplatinumiitetrafluoridoborate AT nesterovvladimirn chlorido444tritertbutyl2262terpyridineplatinumiitetrafluoridoborate AT smuckerbradleyw chlorido444tritertbutyl2262terpyridineplatinumiitetrafluoridoborate |