(4-Acetyl­phenolato)(subphthalo­cyaninato)boron(III)

In the title compound, C(32)H(19)BN(6)O(2), the B atom adopts a BON(3) tetra­hedral coordination geometry. In the crystal, pairs of mol­ecules are associated through aromatic π–π stacking inter­actions between the concave faces of the boronsubphthalocyanine fragments at a centroid–centroid distance...

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Detalles Bibliográficos
Autores principales: Paton, Andrew S., Lough, Alan J., Bender, Timothy P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011621/
https://www.ncbi.nlm.nih.gov/pubmed/21589533
http://dx.doi.org/10.1107/S1600536810046003
Descripción
Sumario:In the title compound, C(32)H(19)BN(6)O(2), the B atom adopts a BON(3) tetra­hedral coordination geometry. In the crystal, pairs of mol­ecules are associated through aromatic π–π stacking inter­actions between the concave faces of the boronsubphthalocyanine fragments at a centroid–centroid distance of 3.4951 (19) Å and a weaker inter­action of the same type between the convex faces of the same group [centroid–centroid separation = 3.5669 (18) Å] also occurs.

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