μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate

In the binuclear title compound, [Mo(2)(C(12)H(15)N(4)O(2))(2)Cl(2)O(3)]·H(2)O, the complex mol­ecules have approximate C (2) symmetry. Both Mo(V) atoms have a distorted octa­hedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand...

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Detalles Bibliográficos
Autores principales: Golobič, Amalija, Čeh, Boris
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011627/
https://www.ncbi.nlm.nih.gov/pubmed/21589316
http://dx.doi.org/10.1107/S1600536810045393
Descripción
Sumario:In the binuclear title compound, [Mo(2)(C(12)H(15)N(4)O(2))(2)Cl(2)O(3)]·H(2)O, the complex mol­ecules have approximate C (2) symmetry. Both Mo(V) atoms have a distorted octa­hedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the Mo(V) atom via an N(2)O donor set. The water mol­ecule bridges two complex mol­ecules, forming O—H⋯O and O—H⋯Cl hydrogen bonds to the acetate group and to the chloride ligands.

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