μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate

In the binuclear title compound, [Mo(2)(C(12)H(15)N(4)O(2))(2)Cl(2)O(3)]·H(2)O, the complex mol­ecules have approximate C (2) symmetry. Both Mo(V) atoms have a distorted octa­hedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand...

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Detalles Bibliográficos
Autores principales: Golobič, Amalija, Čeh, Boris
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011627/
https://www.ncbi.nlm.nih.gov/pubmed/21589316
http://dx.doi.org/10.1107/S1600536810045393
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author Golobič, Amalija
Čeh, Boris
author_facet Golobič, Amalija
Čeh, Boris
author_sort Golobič, Amalija
collection PubMed
description In the binuclear title compound, [Mo(2)(C(12)H(15)N(4)O(2))(2)Cl(2)O(3)]·H(2)O, the complex mol­ecules have approximate C (2) symmetry. Both Mo(V) atoms have a distorted octa­hedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the Mo(V) atom via an N(2)O donor set. The water mol­ecule bridges two complex mol­ecules, forming O—H⋯O and O—H⋯Cl hydrogen bonds to the acetate group and to the chloride ligands.
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spelling pubmed-30116272010-12-30 μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate Golobič, Amalija Čeh, Boris Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the binuclear title compound, [Mo(2)(C(12)H(15)N(4)O(2))(2)Cl(2)O(3)]·H(2)O, the complex mol­ecules have approximate C (2) symmetry. Both Mo(V) atoms have a distorted octa­hedral coordination environment with cis-positioned terminal chloride and oxide groups. The heteroscorpionate organic ligand binds to the Mo(V) atom via an N(2)O donor set. The water mol­ecule bridges two complex mol­ecules, forming O—H⋯O and O—H⋯Cl hydrogen bonds to the acetate group and to the chloride ligands. International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011627/ /pubmed/21589316 http://dx.doi.org/10.1107/S1600536810045393 Text en © Golobič and Čeh 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Golobič, Amalija
Čeh, Boris
μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate
title μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate
title_full μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate
title_fullStr μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate
title_full_unstemmed μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate
title_short μ-Oxido-bis{[2,2-bis­(3,5-dimethyl-1H-pyrazol-1-yl)acetato-κ(3) N (2),O,N (2′)]chloridooxidomolybdenum(V)} mono­hydrate
title_sort μ-oxido-bis{[2,2-bis­(3,5-dimethyl-1h-pyrazol-1-yl)acetato-κ(3) n (2),o,n (2′)]chloridooxidomolybdenum(v)} mono­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011627/
https://www.ncbi.nlm.nih.gov/pubmed/21589316
http://dx.doi.org/10.1107/S1600536810045393
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AT cehboris moxidobis22bis35dimethyl1hpyrazol1ylacetatok3n2on2chloridooxidomolybdenumvmonohydrate

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