Cargando…

{μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III)

In the title dinuclear Cu(II)–Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five...

Descripción completa

Detalles Bibliográficos
Autores principales: Bao, Yan, Li, Guang-Ming, Yang, Fan, Yan, Peng-Fei, Chen, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011629/
https://www.ncbi.nlm.nih.gov/pubmed/21589340
http://dx.doi.org/10.1107/S1600536810048245
_version_ 1782194988146229248
author Bao, Yan
Li, Guang-Ming
Yang, Fan
Yan, Peng-Fei
Chen, Peng
author_facet Bao, Yan
Li, Guang-Ming
Yang, Fan
Yan, Peng-Fei
Chen, Peng
author_sort Bao, Yan
collection PubMed
description In the title dinuclear Cu(II)–Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu—O = 2.230 (3)–2.621 (4) Å]. The slightly distorted square-planar four-coordinate Cu(II) atom comprises two imine N atoms [Cu—N = 1.903 (4) and 1.912 (4) Å] and two phenolate O atoms from the ligand mol­ecule [Cu—O = 1.897 (3) and 1.906 (3) Å]. All atoms of the cyclo­hexane ring of the ligand mol­ecule are disordered over two sets of sites with equal occupancy.
format Text
id pubmed-3011629
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30116292010-12-30 {μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III) Bao, Yan Li, Guang-Ming Yang, Fan Yan, Peng-Fei Chen, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear Cu(II)–Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu—O = 2.230 (3)–2.621 (4) Å]. The slightly distorted square-planar four-coordinate Cu(II) atom comprises two imine N atoms [Cu—N = 1.903 (4) and 1.912 (4) Å] and two phenolate O atoms from the ligand mol­ecule [Cu—O = 1.897 (3) and 1.906 (3) Å]. All atoms of the cyclo­hexane ring of the ligand mol­ecule are disordered over two sets of sites with equal occupancy. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011629/ /pubmed/21589340 http://dx.doi.org/10.1107/S1600536810048245 Text en © Bao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bao, Yan
Li, Guang-Ming
Yang, Fan
Yan, Peng-Fei
Chen, Peng
{μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III)
title {μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III)
title_full {μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III)
title_fullStr {μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III)
title_full_unstemmed {μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III)
title_short {μ-6,6′-Dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(II)lutetium(III)
title_sort {μ-6,6′-dimeth­oxy-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}trinitratocopper(ii)lutetium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011629/
https://www.ncbi.nlm.nih.gov/pubmed/21589340
http://dx.doi.org/10.1107/S1600536810048245
work_keys_str_mv AT baoyan m66dimethoxy22cyclohexane12diylbisnitrilomethylidynediphenolatotrinitratocopperiilutetiumiii
AT liguangming m66dimethoxy22cyclohexane12diylbisnitrilomethylidynediphenolatotrinitratocopperiilutetiumiii
AT yangfan m66dimethoxy22cyclohexane12diylbisnitrilomethylidynediphenolatotrinitratocopperiilutetiumiii
AT yanpengfei m66dimethoxy22cyclohexane12diylbisnitrilomethylidynediphenolatotrinitratocopperiilutetiumiii
AT chenpeng m66dimethoxy22cyclohexane12diylbisnitrilomethylidynediphenolatotrinitratocopperiilutetiumiii