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{μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III)
In the title dinuclear Cu(II)–Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011629/ https://www.ncbi.nlm.nih.gov/pubmed/21589340 http://dx.doi.org/10.1107/S1600536810048245 |
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author | Bao, Yan Li, Guang-Ming Yang, Fan Yan, Peng-Fei Chen, Peng |
author_facet | Bao, Yan Li, Guang-Ming Yang, Fan Yan, Peng-Fei Chen, Peng |
author_sort | Bao, Yan |
collection | PubMed |
description | In the title dinuclear Cu(II)–Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu—O = 2.230 (3)–2.621 (4) Å]. The slightly distorted square-planar four-coordinate Cu(II) atom comprises two imine N atoms [Cu—N = 1.903 (4) and 1.912 (4) Å] and two phenolate O atoms from the ligand molecule [Cu—O = 1.897 (3) and 1.906 (3) Å]. All atoms of the cyclohexane ring of the ligand molecule are disordered over two sets of sites with equal occupancy. |
format | Text |
id | pubmed-3011629 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116292010-12-30 {μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III) Bao, Yan Li, Guang-Ming Yang, Fan Yan, Peng-Fei Chen, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear Cu(II)–Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu—O = 2.230 (3)–2.621 (4) Å]. The slightly distorted square-planar four-coordinate Cu(II) atom comprises two imine N atoms [Cu—N = 1.903 (4) and 1.912 (4) Å] and two phenolate O atoms from the ligand molecule [Cu—O = 1.897 (3) and 1.906 (3) Å]. All atoms of the cyclohexane ring of the ligand molecule are disordered over two sets of sites with equal occupancy. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011629/ /pubmed/21589340 http://dx.doi.org/10.1107/S1600536810048245 Text en © Bao et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Bao, Yan Li, Guang-Ming Yang, Fan Yan, Peng-Fei Chen, Peng {μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III) |
title | {μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III) |
title_full | {μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III) |
title_fullStr | {μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III) |
title_full_unstemmed | {μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III) |
title_short | {μ-6,6′-Dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)lutetium(III) |
title_sort | {μ-6,6′-dimethoxy-2,2′-[cyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(ii)lutetium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011629/ https://www.ncbi.nlm.nih.gov/pubmed/21589340 http://dx.doi.org/10.1107/S1600536810048245 |
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