(E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one

In the title mol­ecule, C(18)H(15)NO(2), the carbazole unit is not planar [maximum deviation from mean plane = 0.236 (2) Å]. The pyrrole ring makes dihedral angles of 1.21 (10) and 16.74 (12)° with the benzene and the furan rings, respectively. The cyclo­hexene ring adopts a half-chair conformation....

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Detalles Bibliográficos
Autores principales: Archana, R., Yamuna, E., Rajendra Prasad, K. J., Thiruvalluvar, A., Butcher, R. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011638/
https://www.ncbi.nlm.nih.gov/pubmed/21589444
http://dx.doi.org/10.1107/S1600536810045599
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author Archana, R.
Yamuna, E.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_facet Archana, R.
Yamuna, E.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
author_sort Archana, R.
collection PubMed
description In the title mol­ecule, C(18)H(15)NO(2), the carbazole unit is not planar [maximum deviation from mean plane = 0.236 (2) Å]. The pyrrole ring makes dihedral angles of 1.21 (10) and 16.74 (12)° with the benzene and the furan rings, respectively. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(10) loops.
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spelling pubmed-30116382010-12-30 (E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one Archana, R. Yamuna, E. Rajendra Prasad, K. J. Thiruvalluvar, A. Butcher, R. J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(18)H(15)NO(2), the carbazole unit is not planar [maximum deviation from mean plane = 0.236 (2) Å]. The pyrrole ring makes dihedral angles of 1.21 (10) and 16.74 (12)° with the benzene and the furan rings, respectively. The cyclo­hexene ring adopts a half-chair conformation. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(10) loops. International Union of Crystallography 2010-11-13 /pmc/articles/PMC3011638/ /pubmed/21589444 http://dx.doi.org/10.1107/S1600536810045599 Text en © Archana et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Archana, R.
Yamuna, E.
Rajendra Prasad, K. J.
Thiruvalluvar, A.
Butcher, R. J.
(E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title (E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_full (E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_fullStr (E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_full_unstemmed (E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_short (E)-2-(Furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1H-carbazol-1-one
title_sort (e)-2-(furan-2-yl­methyl­idene)-8-methyl-2,3,4,9-tetra­hydro-1h-carbazol-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011638/
https://www.ncbi.nlm.nih.gov/pubmed/21589444
http://dx.doi.org/10.1107/S1600536810045599
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