1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene

The asymmetric unit of the title compound, C(36)H(24)N(6), comprises a whole mol­ecule. Supra­molecular inter­actions between neighbouring mol­ecules are essentially π–π stacking inter­actions with small inter­planar distances [3.5140 (15) and 3.6041 (15) Å]. The central phenyl­ene ring is tilted wi...

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Detalles Bibliográficos
Autores principales: Fernandes, José A., Almeida Paz, Filipe A., Lima, Patrícia P., Alves Jr, Severino, Carlos, Luís D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011639/
https://www.ncbi.nlm.nih.gov/pubmed/21589530
http://dx.doi.org/10.1107/S1600536810047598
Descripción
Sumario:The asymmetric unit of the title compound, C(36)H(24)N(6), comprises a whole mol­ecule. Supra­molecular inter­actions between neighbouring mol­ecules are essentially π–π stacking inter­actions with small inter­planar distances [3.5140 (15) and 3.6041 (15) Å]. The central phenyl­ene ring is tilted with respect to the two pyridine substituents, subtending angles of 36.17 (11) and 34.95 (11)°. Three of the peripheral pyridine substituents are almost coplanar with the central pyridines [dihedral angles = 5.10 (12)-8.21 (12)°], but one subtends an angle of 24.86 (12)°.

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