1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene

The asymmetric unit of the title compound, C(36)H(24)N(6), comprises a whole mol­ecule. Supra­molecular inter­actions between neighbouring mol­ecules are essentially π–π stacking inter­actions with small inter­planar distances [3.5140 (15) and 3.6041 (15) Å]. The central phenyl­ene ring is tilted wi...

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Autores principales: Fernandes, José A., Almeida Paz, Filipe A., Lima, Patrícia P., Alves Jr, Severino, Carlos, Luís D.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011639/
https://www.ncbi.nlm.nih.gov/pubmed/21589530
http://dx.doi.org/10.1107/S1600536810047598
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author Fernandes, José A.
Almeida Paz, Filipe A.
Lima, Patrícia P.
Alves Jr, Severino
Carlos, Luís D.
author_facet Fernandes, José A.
Almeida Paz, Filipe A.
Lima, Patrícia P.
Alves Jr, Severino
Carlos, Luís D.
author_sort Fernandes, José A.
collection PubMed
description The asymmetric unit of the title compound, C(36)H(24)N(6), comprises a whole mol­ecule. Supra­molecular inter­actions between neighbouring mol­ecules are essentially π–π stacking inter­actions with small inter­planar distances [3.5140 (15) and 3.6041 (15) Å]. The central phenyl­ene ring is tilted with respect to the two pyridine substituents, subtending angles of 36.17 (11) and 34.95 (11)°. Three of the peripheral pyridine substituents are almost coplanar with the central pyridines [dihedral angles = 5.10 (12)-8.21 (12)°], but one subtends an angle of 24.86 (12)°.
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spelling pubmed-30116392010-12-30 1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene Fernandes, José A. Almeida Paz, Filipe A. Lima, Patrícia P. Alves Jr, Severino Carlos, Luís D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(36)H(24)N(6), comprises a whole mol­ecule. Supra­molecular inter­actions between neighbouring mol­ecules are essentially π–π stacking inter­actions with small inter­planar distances [3.5140 (15) and 3.6041 (15) Å]. The central phenyl­ene ring is tilted with respect to the two pyridine substituents, subtending angles of 36.17 (11) and 34.95 (11)°. Three of the peripheral pyridine substituents are almost coplanar with the central pyridines [dihedral angles = 5.10 (12)-8.21 (12)°], but one subtends an angle of 24.86 (12)°. International Union of Crystallography 2010-11-20 /pmc/articles/PMC3011639/ /pubmed/21589530 http://dx.doi.org/10.1107/S1600536810047598 Text en © Fernandes et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fernandes, José A.
Almeida Paz, Filipe A.
Lima, Patrícia P.
Alves Jr, Severino
Carlos, Luís D.
1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene
title 1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene
title_full 1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene
title_fullStr 1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene
title_full_unstemmed 1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene
title_short 1,4-Bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene
title_sort 1,4-bis(2,2′:6′,2′′-terpyridin-4′-yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011639/
https://www.ncbi.nlm.nih.gov/pubmed/21589530
http://dx.doi.org/10.1107/S1600536810047598
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AT carlosluisd 14bis2262terpyridin4ylbenzene

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