Cargando…
2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate
In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-aminopyridine and 1-phenylcyclopropane-1-carboxylic acid crystallize together, forming a 2-aminopyridinium–carboxylate supramolecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component su...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011640/ https://www.ncbi.nlm.nih.gov/pubmed/21589613 http://dx.doi.org/10.1107/S1600536810049093 |
Sumario: | In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-aminopyridine and 1-phenylcyclopropane-1-carboxylic acid crystallize together, forming a 2-aminopyridinium–carboxylate supramolecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component supramolecular unit also sustained by N—H⋯O hydrogen bonding. A C—H⋯π interaction between a pyridine C—H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supramolecular unit. The overall crystal packing also features C—H⋯O interactions. |
---|