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2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate

In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-amino­pyridine and 1-phenyl­cyclo­propane-1-carb­oxy­lic acid crystallize together, forming a 2-amino­pyridinium–carboxyl­ate supra­molecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component su...

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Detalles Bibliográficos
Autores principales: He, Guangwen, Aitipamula, Srinivasulu, Chow, Pui Shan, Tan, Reginald B. H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011640/
https://www.ncbi.nlm.nih.gov/pubmed/21589613
http://dx.doi.org/10.1107/S1600536810049093
Descripción
Sumario:In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-amino­pyridine and 1-phenyl­cyclo­propane-1-carb­oxy­lic acid crystallize together, forming a 2-amino­pyridinium–carboxyl­ate supra­molecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component supra­molecular unit also sustained by N—H⋯O hydrogen bonding. A C—H⋯π inter­action between a pyridine C—H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supra­molecular unit. The overall crystal packing also features C—H⋯O inter­actions.