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2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate
In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-aminopyridine and 1-phenylcyclopropane-1-carboxylic acid crystallize together, forming a 2-aminopyridinium–carboxylate supramolecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component su...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011640/ https://www.ncbi.nlm.nih.gov/pubmed/21589613 http://dx.doi.org/10.1107/S1600536810049093 |
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author | He, Guangwen Aitipamula, Srinivasulu Chow, Pui Shan Tan, Reginald B. H. |
author_facet | He, Guangwen Aitipamula, Srinivasulu Chow, Pui Shan Tan, Reginald B. H. |
author_sort | He, Guangwen |
collection | PubMed |
description | In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-aminopyridine and 1-phenylcyclopropane-1-carboxylic acid crystallize together, forming a 2-aminopyridinium–carboxylate supramolecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component supramolecular unit also sustained by N—H⋯O hydrogen bonding. A C—H⋯π interaction between a pyridine C—H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supramolecular unit. The overall crystal packing also features C—H⋯O interactions. |
format | Text |
id | pubmed-3011640 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30116402010-12-30 2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate He, Guangwen Aitipamula, Srinivasulu Chow, Pui Shan Tan, Reginald B. H. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-aminopyridine and 1-phenylcyclopropane-1-carboxylic acid crystallize together, forming a 2-aminopyridinium–carboxylate supramolecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component supramolecular unit also sustained by N—H⋯O hydrogen bonding. A C—H⋯π interaction between a pyridine C—H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supramolecular unit. The overall crystal packing also features C—H⋯O interactions. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011640/ /pubmed/21589613 http://dx.doi.org/10.1107/S1600536810049093 Text en © He et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers He, Guangwen Aitipamula, Srinivasulu Chow, Pui Shan Tan, Reginald B. H. 2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate |
title | 2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate |
title_full | 2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate |
title_fullStr | 2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate |
title_full_unstemmed | 2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate |
title_short | 2-Aminopyridinium 1-phenylcyclopropane-1-carboxylate |
title_sort | 2-aminopyridinium 1-phenylcyclopropane-1-carboxylate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011640/ https://www.ncbi.nlm.nih.gov/pubmed/21589613 http://dx.doi.org/10.1107/S1600536810049093 |
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