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2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate

In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-amino­pyridine and 1-phenyl­cyclo­propane-1-carb­oxy­lic acid crystallize together, forming a 2-amino­pyridinium–carboxyl­ate supra­molecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component su...

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Detalles Bibliográficos
Autores principales: He, Guangwen, Aitipamula, Srinivasulu, Chow, Pui Shan, Tan, Reginald B. H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011640/
https://www.ncbi.nlm.nih.gov/pubmed/21589613
http://dx.doi.org/10.1107/S1600536810049093
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author He, Guangwen
Aitipamula, Srinivasulu
Chow, Pui Shan
Tan, Reginald B. H.
author_facet He, Guangwen
Aitipamula, Srinivasulu
Chow, Pui Shan
Tan, Reginald B. H.
author_sort He, Guangwen
collection PubMed
description In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-amino­pyridine and 1-phenyl­cyclo­propane-1-carb­oxy­lic acid crystallize together, forming a 2-amino­pyridinium–carboxyl­ate supra­molecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component supra­molecular unit also sustained by N—H⋯O hydrogen bonding. A C—H⋯π inter­action between a pyridine C—H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supra­molecular unit. The overall crystal packing also features C—H⋯O inter­actions.
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spelling pubmed-30116402010-12-30 2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate He, Guangwen Aitipamula, Srinivasulu Chow, Pui Shan Tan, Reginald B. H. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (−), 2-amino­pyridine and 1-phenyl­cyclo­propane-1-carb­oxy­lic acid crystallize together, forming a 2-amino­pyridinium–carboxyl­ate supra­molecular heterosynthon involving two N—H⋯O hydrogen bonds, which in turn dimerizes to form a four-component supra­molecular unit also sustained by N—H⋯O hydrogen bonding. A C—H⋯π inter­action between a pyridine C—H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supra­molecular unit. The overall crystal packing also features C—H⋯O inter­actions. International Union of Crystallography 2010-11-27 /pmc/articles/PMC3011640/ /pubmed/21589613 http://dx.doi.org/10.1107/S1600536810049093 Text en © He et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Guangwen
Aitipamula, Srinivasulu
Chow, Pui Shan
Tan, Reginald B. H.
2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate
title 2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate
title_full 2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate
title_fullStr 2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate
title_full_unstemmed 2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate
title_short 2-Amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate
title_sort 2-amino­pyridinium 1-phenyl­cyclo­propane-1-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011640/
https://www.ncbi.nlm.nih.gov/pubmed/21589613
http://dx.doi.org/10.1107/S1600536810049093
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AT tanreginaldbh 2aminopyridinium1phenylcyclopropane1carboxylate