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7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate

In the title compound, C(24)H(18)N(2)O(4)·CHCl(3), the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The mol­ecule has a Z configuration about the C=N bond...

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Detalles Bibliográficos
Autores principales: Nagasawa, Atsushi, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011643/
https://www.ncbi.nlm.nih.gov/pubmed/21589563
http://dx.doi.org/10.1107/S1600536810048002
Descripción
Sumario:In the title compound, C(24)H(18)N(2)O(4)·CHCl(3), the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The mol­ecule has a Z configuration about the C=N bond. In the crystal, mol­ecules are linked by inter­molecular O—H⋯N=C hydrogen bonds between the imino moiety and hy­droxy groups. Inter­molecular C—Cl⋯C inter­actions between Cl atoms of the CHCl(3) mol­ecule and C atoms of the naphthalene rings are also present [Cl⋯C = 3.353 (2) and 3.326 (19) Å]. The nitro group and the chloro­form solvent mol­ecule are disordered over two positions with site occupancies of 0.884 (4) and 0.116 (4).