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7-Methoxy-1-{[(Z)-2-nitrophenylimino](phenyl)methyl}-2-naphthol chloroform monosolvate
In the title compound, C(24)H(18)N(2)O(4)·CHCl(3), the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The molecule has a Z configuration about the C=N bond...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011643/ https://www.ncbi.nlm.nih.gov/pubmed/21589563 http://dx.doi.org/10.1107/S1600536810048002 |
Sumario: | In the title compound, C(24)H(18)N(2)O(4)·CHCl(3), the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The molecule has a Z configuration about the C=N bond. In the crystal, molecules are linked by intermolecular O—H⋯N=C hydrogen bonds between the imino moiety and hydroxy groups. Intermolecular C—Cl⋯C interactions between Cl atoms of the CHCl(3) molecule and C atoms of the naphthalene rings are also present [Cl⋯C = 3.353 (2) and 3.326 (19) Å]. The nitro group and the chloroform solvent molecule are disordered over two positions with site occupancies of 0.884 (4) and 0.116 (4). |
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