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7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate

In the title compound, C(24)H(18)N(2)O(4)·CHCl(3), the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The mol­ecule has a Z configuration about the C=N bond...

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Detalles Bibliográficos
Autores principales: Nagasawa, Atsushi, Okamoto, Akiko, Yonezawa, Noriyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011643/
https://www.ncbi.nlm.nih.gov/pubmed/21589563
http://dx.doi.org/10.1107/S1600536810048002
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author Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_facet Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
author_sort Nagasawa, Atsushi
collection PubMed
description In the title compound, C(24)H(18)N(2)O(4)·CHCl(3), the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The mol­ecule has a Z configuration about the C=N bond. In the crystal, mol­ecules are linked by inter­molecular O—H⋯N=C hydrogen bonds between the imino moiety and hy­droxy groups. Inter­molecular C—Cl⋯C inter­actions between Cl atoms of the CHCl(3) mol­ecule and C atoms of the naphthalene rings are also present [Cl⋯C = 3.353 (2) and 3.326 (19) Å]. The nitro group and the chloro­form solvent mol­ecule are disordered over two positions with site occupancies of 0.884 (4) and 0.116 (4).
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spelling pubmed-30116432010-12-30 7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate Nagasawa, Atsushi Okamoto, Akiko Yonezawa, Noriyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(18)N(2)O(4)·CHCl(3), the phenyl and benzene rings make a dihedral angle of 38.60 (9)° and connect in an orientation almost perpendicular to the naphthalene ring system at dihedral angles of 78.73 (8) and 81.20 (7)°. The mol­ecule has a Z configuration about the C=N bond. In the crystal, mol­ecules are linked by inter­molecular O—H⋯N=C hydrogen bonds between the imino moiety and hy­droxy groups. Inter­molecular C—Cl⋯C inter­actions between Cl atoms of the CHCl(3) mol­ecule and C atoms of the naphthalene rings are also present [Cl⋯C = 3.353 (2) and 3.326 (19) Å]. The nitro group and the chloro­form solvent mol­ecule are disordered over two positions with site occupancies of 0.884 (4) and 0.116 (4). International Union of Crystallography 2010-11-24 /pmc/articles/PMC3011643/ /pubmed/21589563 http://dx.doi.org/10.1107/S1600536810048002 Text en © Nagasawa et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nagasawa, Atsushi
Okamoto, Akiko
Yonezawa, Noriyuki
7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate
title 7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate
title_full 7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate
title_fullStr 7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate
title_full_unstemmed 7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate
title_short 7-Meth­oxy-1-{[(Z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate
title_sort 7-meth­oxy-1-{[(z)-2-nitro­phenyl­imino](phen­yl)meth­yl}-2-naphthol chloro­form monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3011643/
https://www.ncbi.nlm.nih.gov/pubmed/21589563
http://dx.doi.org/10.1107/S1600536810048002
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AT okamotoakiko 7methoxy1z2nitrophenyliminophenylmethyl2naphtholchloroformmonosolvate
AT yonezawanoriyuki 7methoxy1z2nitrophenyliminophenylmethyl2naphtholchloroformmonosolvate